I-Rh[5,10,15-trimesityl-20-[4-[5-(p-(10,15,20-trimesityl-5-porphinyl)-2,6-dimethylphenoxy)pentoxy]-2,6-dimethylphenyl]porphinato]Rh-I

Base Information

Chemical Name:I-Rh[5,10,15-trimesityl-20-[4-[5-(p-(10,15,20-trimesityl-5-porphinyl)-2,6-dimethylphenoxy)pentoxy]-2,6-dimethylphenyl]porphinato]Rh-I
CAS No.:312911-82-3
Molecular Formula:C₁₁₅H₁₀₈I₂N₈O₂Rh₂
Molecular Weight:2093.79
Hs Code.:

Synonyms:I-Rh[5,10,15-trimesityl-20-[4-[5-(p-(10,15,20-trimesityl-5-porphinyl)-2,6-dimethylphenoxy)pentoxy]-2,6-dimethylphenyl]porphinato]Rh-I

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Chemical Property of I-Rh[5,10,15-trimesityl-20-[4-[5-(p-(10,15,20-trimesityl-5-porphinyl)-2,6-dimethylphenoxy)pentoxy]-2,6-dimethylphenyl]porphinato]Rh-I

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Technology Process of I-Rh[5,10,15-trimesityl-20-[4-[5-(p-(10,15,20-trimesityl-5-porphinyl)-2,6-dimethylphenoxy)pentoxy]-2,6-dimethylphenyl]porphinato]Rh-I

There total 1 articles about I-Rh[5,10,15-trimesityl-20-[4-[5-(p-(10,15,20-trimesityl-5-porphinyl)-2,6-dimethylphenoxy)pentoxy]-2,6-dimethylphenyl]porphinato]Rh-I which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: di(rhodium)tetracarbonyl dichloride

: 5,10,15-trimesityl-20-[4-[5-(p-(10,15,20-trimesityl-5-porphinyl)-2,6-dimethylphenoxy)pentoxy]-2,6-dimethylphenyl]porphine

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 312911-82-3
I-Rh[5,10,15-trimesityl-20-[4-[5-(p-(10,15,20-trimesityl-5-porphinyl)-2,6-dimethylphenoxy)pentoxy]-2,6-dimethylphenyl]porphinato]Rh-I

Guidance literature:: With sodium acetate; In 1,2-dichloro-ethane; (vac. or Ar); Rh complex soln. added dropwise to suspn. contg. ligand and anhyd. NaOAc, refluxed, cooled to room temp., I2 added in two portions, stirred at room temp.; filtered, concd., treated with CH2Cl2 and satd. Na2S2O3 aq. soln., org.phase concd., chromd. (SiO2, CH2Cl2/hexane);
DOI:10.1021/ic0006302

Reference yield: 84.0%

: 312911-82-3
I-Rh[5,10,15-trimesityl-20-[4-[5-(p-(10,15,20-trimesityl-5-porphinyl)-2,6-dimethylphenoxy)pentoxy]-2,6-dimethylphenyl]porphinato]Rh-I

: 74-88-4
methyl iodide

: 312911-91-4
H₃C-Rh[5,10,15-trimesityl-20-[4-[5-(p-(10,15,20-trimesityl-5-porphinyl)-2,6-dimethylphenoxy)pentoxy]-2,6-dimethylphenyl]porphinato]Rh-CH₃

Guidance literature:: With sodium tetrahydroborate; In sodium hydroxide; ethanol; (vac. or Ar); Rh complex dissolved in EtOH by sttirring at 60°C,filtered in air, flushed with Ar, excess of NaBH4 in aq. NaOH added, stirred, CH3I added; ppt. filtered off, chromd. (SiO2, C6H6);
DOI:10.1021/ic0006302