(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)]B(C₆H₅)4

Base Information

• Chemical Name: (N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)]B(C₆H₅)4
• CAS No.: 95099-93-7
• Molecular Formula: C₂₄H₂₀B*C₄₅H₄₇NNiO₂P₃
• Molecular Weight: 1104.72
• Mol file: 95099-93-7.mol

Synonyms:(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)]B(C₆H₅)4

Chemical Property of (N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)]B(C₆H₅)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)]B(C₆H₅)4

There total 3 articles about (N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)]B(C₆H₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

(tris(2-diphenylphosphinoethyl)amine)nickel(0) (52633-73-5,97135-31-4) + sodium tetraphenyl borate (143-66-8) + ethyl cyanoformate (623-49-4) → (N(CH2CH2P(C6H5)2)3)Ni(CO2C2H5)(1+)*B(C6H5)4(1-)=[(N(CH2CH2P(C6H5)2)3)Ni(CO2C2H5)]B(C6H5)4 (95099-93-7)

Guidance literature:

In tetrahydrofuran; acetone; byproducts: NaCN; N2-atmosphere; addn. of NCCO2Et to Ni-complex (in THF), evapn. (after 10 min, vac.), addn. of NaBPh4 in acetone; pptn. with n-BuOH/n-Bu2O mixt. (1:3), immediate filtration; washing (ethanol/petroleum ether), drying, elem. anal.;

DOI:10.1021/om00139a026

Reference yield: 20.0%

{(C6H5)2PCH2CH2}3NNiCO (88440-32-8) + sodium ethanolate (141-52-6) + sodium tetraphenyl borate (143-66-8) → (N(CH2CH2P(C6H5)2)3)Ni(CO2C2H5)(1+)*B(C6H5)4(1-)=[(N(CH2CH2P(C6H5)2)3)Ni(CO2C2H5)]B(C6H5)4 (95099-93-7)

Guidance literature:

With air; In tetrahydrofuran; ethanol; C2H5ONa in EtOH added to complex soln. in THF, stirred for 1 h, soln. of NaB(C6H5)4 in EtOH added, exposed to air for 4 h; left overnight;

DOI:10.1016/0022-328X(84)80663-4

Reference yield: 15.0%

[(((C6H5)2PCH2CH2)3N)Ni(CO)](1+)*B(C6H5)4(1-)=[(((C6H5)2PCH2CH2)3N)Ni(CO)]B(C6H5)4 (88510-50-3) + sodium ethanolate (141-52-6) → {(C6H5)2PCH2CH2}3NNiCO (88440-32-8) + (N(CH2CH2P(C6H5)2)3)Ni(CO2C2H5)(1+)*B(C6H5)4(1-)=[(N(CH2CH2P(C6H5)2)3)Ni(CO2C2H5)]B(C6H5)4 (95099-93-7)

Guidance literature:

In tetrahydrofuran; ethanol; (N2); to suspn. of complex in THF added soln. of C2H5ONa in EtOH; butanol added, concd.;

DOI:10.1016/0022-328X(84)80663-4

upstream raw materials:

[(((C₆H₅)2PCH₂CH₂)3N)Ni(CO)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(((C₆H₅)2PCH₂CH₂)3N)Ni(CO)]B(C₆H₅)4

sodium ethanolate

{(C₆H₅)2PCH₂CH₂}3NNiCO

sodium tetraphenyl borate

Downstream raw materials:

[(((C₆H₅)2PCH₂CH₂)3NH)Ni(CO)]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(((C₆H₅)2PCH₂CH₂)3NH)Ni(CO)]B(C₆H₅)4

[(((C₆H₅)2PCH₂CH₂)3N)NiH]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(((C₆H₅)2PCH₂CH₂)3N)NiH]B(C₆H₅)4

{(C₆H₅)2PCH₂CH₂}3NNiCO

(N(CH₂CH₂P(C₆H₅)2)3)Ni(CN)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(N(CH₂CH₂P(C₆H₅)2)3)Ni(CN)]B(C₆H₅)4