[(π-C5H5)Fe(CO)2(P(C6H5)3)](1+)

Base Information

Chemical Name:[(π-C5H5)Fe(CO)2(P(C6H5)3)](1+)
CAS No.:32626-58-7
Molecular Formula:C₂₅H₂₀FeO₂P
Molecular Weight:439.253
Hs Code.:

Synonyms:[(π-C5H5)Fe(CO)2(P(C6H5)3)](1+)

Suppliers and Price of [(π-C5H5)Fe(CO)2(P(C6H5)3)](1+)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(π-C5H5)Fe(CO)2(P(C6H5)3)](1+)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [(π-C5H5)Fe(CO)2(P(C6H5)3)](1+)

There total 11 articles about [(π-C5H5)Fe(CO)2(P(C6H5)3)](1+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: (η-C5H5)Fe(CO){P(Ph)3}COOK

: 32626-58-7
[(π-C5H5)Fe(CO)2(P(C6H5)3)](1+)

: (C₅H₅)Fe(P(C₆H₅)3)(CO)(C(O)OCH₃)

Guidance literature:: With methyl iodide; In acetonitrile; (N2); cold soln. of alkylating agent was added to solid Fe complex at -30 - -40°C, mixt. was stirred at low temp. and then slowly warmed up to room temp.; solvent was removed and residue was taken up in CH2Cl2/hexane;
DOI:10.1021/ja00257a049

Reference yield: 70.0%

: (η-C5H5)Fe(CO){P(Ph)3}COOK

: 333-27-7
methyl trifluoromethanesulfonate

: 32626-58-7
[(π-C5H5)Fe(CO)2(P(C6H5)3)](1+)

: (C₅H₅)Fe(P(C₆H₅)3)(CO)(C(O)OCH₃)

Guidance literature:: In acetonitrile; (N2); cold soln. of alkylating agent was added to solid Fe complex at -30 - -40°C, mixt. was stirred at low temp. and then slowly warmed up to room temp.; solvent was removed and residue was taken up in CH2Cl2/hexane;
DOI:10.1021/ja00257a049

Reference yield: 11.0%

: (C₅H₅)Fe(CO)(P(C₆H₅)3)CF₃

: 7637-07-2
boron trifluoride

: 32626-58-7
[(π-C5H5)Fe(CO)2(P(C6H5)3)](1+)

: (C₅H₅)Fe(CO)(P(C₆H₅)3)CF₂⁽¹⁺⁾*BF₄^(1-)=(C₅H₅)Fe(CO)(P(C₆H₅)3)CF₂BF₄

Guidance literature:: In dichloromethane; treating of the starting complex soln. with BF3 under inert atm., solvent slowly evapg.; identified by elem. anal., IR, NMR spectra and single crystal X-ray diffraction;