platinum(II) 5,15-bis(pentafluorophenyl)-10,20-bis(4-bromophenyl)porphyrin

Base Information

Chemical Name:platinum(II) 5,15-bis(pentafluorophenyl)-10,20-bis(4-bromophenyl)porphyrin
CAS No.:1374238-64-8
Molecular Formula:C₄₄H₁₆Br₂F₁₀N₄Pt
Molecular Weight:1145.51
Hs Code.:

Synonyms:platinum(II) 5,15-bis(pentafluorophenyl)-10,20-bis(4-bromophenyl)porphyrin

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Chemical Property of platinum(II) 5,15-bis(pentafluorophenyl)-10,20-bis(4-bromophenyl)porphyrin

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Technology Process of platinum(II) 5,15-bis(pentafluorophenyl)-10,20-bis(4-bromophenyl)porphyrin

There total 3 articles about platinum(II) 5,15-bis(pentafluorophenyl)-10,20-bis(4-bromophenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 5,15-bis(4-bromophenyl)-10,20-bis(pentafluorophenyl)-porphyrin

: 1374238-64-8
platinum(II) 5,15-bis(pentafluorophenyl)-10,20-bis(4-bromophenyl)porphyrin

Guidance literature:: With potassium tetrachloroplatinate(II); In benzonitrile; at 180 ℃; for 48h; Inert atmosphere;
DOI:10.1021/ic300040n

Reference yield: 72.0%

: 10025-99-7
potassium tetrachloroplatinate(II)

: 5,15-bis(4-bromophenyl)-10,20-bis(pentafluorophenyl)-porphyrin

: 1374238-64-8
platinum(II) 5,15-bis(pentafluorophenyl)-10,20-bis(4-bromophenyl)porphyrin

Guidance literature:: In benzonitrile; (N2) soln. K2(PtCl4) and ligand in benzonitrile was heated under reflux at 180°C for 2 days; react. mixt. was cooled, solvent was removed in vacuo, column chromy. onsilica (CH2Cl2-hexane 1:2), solvent was removed in vacuo, residue was r ecrystd.; elem. anal.;
DOI:10.1021/ic300040n

Reference yield:

: 653-37-2
perfluorobenzaldehyde

: 1374238-64-8
platinum(II) 5,15-bis(pentafluorophenyl)-10,20-bis(4-bromophenyl)porphyrin

Guidance literature:: Multi-step reaction with 3 steps

1.1: trifluoroacetic acid / 0.25 h / 20 °C / Inert atmosphere

2.1: boron trifluoride diethyl etherate / dichloromethane / 1.17 h / 20 °C / Inert atmosphere

2.2: 1 h / 20 °C / Inert atmosphere

3.1: potassium tetrachloroplatinate(II) / benzonitrile / 48 h / 180 °C / Inert atmosphere

With potassium tetrachloroplatinate(II); boron trifluoride diethyl etherate; trifluoroacetic acid; In dichloromethane; benzonitrile;
DOI:10.1021/ic300040n