[5-(4',4',5',5'-tetramethyl[1',3',2']-dioxaborolan-2'-yl)-10,20-diphenylporphyrinato]zinc(II)

Base Information

Chemical Name:[5-(4',4',5',5'-tetramethyl[1',3',2']-dioxaborolan-2'-yl)-10,20-diphenylporphyrinato]zinc(II)
CAS No.:219640-18-3
Molecular Formula:C₃₈H₃₁BN₄O₂Zn
Molecular Weight:651.891
Hs Code.:

Synonyms:[5-(4',4',5',5'-tetramethyl[1',3',2']-dioxaborolan-2'-yl)-10,20-diphenylporphyrinato]zinc(II)

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Chemical Property of [5-(4',4',5',5'-tetramethyl[1',3',2']-dioxaborolan-2'-yl)-10,20-diphenylporphyrinato]zinc(II)

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Technology Process of [5-(4',4',5',5'-tetramethyl[1',3',2']-dioxaborolan-2'-yl)-10,20-diphenylporphyrinato]zinc(II)

There total 1 articles about [5-(4',4',5',5'-tetramethyl[1',3',2']-dioxaborolan-2'-yl)-10,20-diphenylporphyrinato]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: zinc(II) acetate tetrahydrate

: 5,15-diphenyl-10-(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)porphyrin

: 219640-18-3
[5-(4',4',5',5'-tetramethyl[1',3',2']-dioxaborolan-2'-yl)-10,20-diphenylporphyrinato]zinc(II)

Guidance literature:: With triethylamine; In 1,2-dichloro-ethane; for 2h; Reflux; Inert atmosphere;
DOI:10.1021/jp405976h

Reference yield: 92.0%

: 219640-18-3
[5-(4',4',5',5'-tetramethyl[1',3',2']-dioxaborolan-2'-yl)-10,20-diphenylporphyrinato]zinc(II)

: 219590-17-7
1-iodo-8-(2,5-dimethoxyphenyl)naphthalene

: (5,15-diphenylporphinato)zinc(II)

: 219640-22-9
[5-(8'-[2'',5''-dimethoxyphenyl]-1'-naphthyl)-10,20-diphenylporphinato]zinc(II)

Guidance literature:: With barium dihydroxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,2-dimethoxyethane; water; ligand, Zn-complex and Ba(OH)2*8H2O were dissolved in H2O and DME, Pd-complex was added, mixt. was heated at 80°C for 6 h under N2; quenched, loaded onto silica gel column with hexane/THF, volatiles wereremoved, washed with hexane, vac. filtered;
DOI:10.1021/ja000759a

Reference yield: 81.0%

: 219640-18-3
[5-(4',4',5',5'-tetramethyl[1',3',2']-dioxaborolan-2'-yl)-10,20-diphenylporphyrinato]zinc(II)

: 303006-88-4
1-iodo-8-[4'-(8''-[2''',5'''-dimethoxyphenyl]-1''-naphthyl)-1'-phenyl]naphthalene

: (5,15-diphenylporphinato)zinc(II)

: 303052-58-6
[5-[8'-(4''-[8'''-(2'''',5''''-dimethoxyphenyl)-1'''-naphthyl]-1''-phenyl)-1'-naphthyl]-10,20-diphenylporphinato]zinc(II)

Guidance literature:: With barium dihydroxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,2-dimethoxyethane; water; ligand, Zn-complex and Ba(OH)2*8H2O were dissolved in H2O and DME, Pd-complex was added, mixt. was heated at 80°C for 1 h under N2; benzene and satd. soln. of NaCl were added, organic layer was washed with NaCl and H2O, dried over CaCl2, filtered, evapd., chromy. on silica gel with hexane/THF;
DOI:10.1021/ja000759a