bis(cycloocta-1,5-diene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate

Base Information

Chemical Name:bis(cycloocta-1,5-diene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate
CAS No.:404573-66-6
Molecular Formula:C₁₆H₂₄Rh*C₃₂H₁₂BF₂₄
Molecular Weight:1182.49
Hs Code.:

Synonyms:bis(cycloocta-1,5-diene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate

Suppliers and Price of bis(cycloocta-1,5-diene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 4 raw suppliers

Chemical Property of bis(cycloocta-1,5-diene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate

Chemical Property:

Purity/Quality:: 97% ^*data from raw suppliers

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Technology Process of bis(cycloocta-1,5-diene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate

There total 3 articles about bis(cycloocta-1,5-diene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 5259-72-3,10060-40-9,111-78-4
cyclo-octa-1,5-diene

: 404573-66-6
bis(1,5-cyclooctadiene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Guidance literature:: In dichloromethane; byproducts: NaCl; (N2); Rh complex and ligand dissolved in CH2Cl2, Na salt/CH2Cl2 added dropwise at 25°C, stirred for 20 min; filtered (MgSO4), added to hexane, crystals filtered off under N2, recrystd. (CH2Cl2/hexane); elem. anal.;
DOI:10.1016/S0020-1693(01)00601-6

Reference yield: 89.0%

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 5259-72-3,10060-40-9,111-78-4
cyclo-octa-1,5-diene

: 404573-66-6
bis(cycloocta-1,5-diene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]-borate

Guidance literature:: In dichloromethane; for 0.333333h; Inert atmosphere; Glovebox; Schlenk technique;
DOI:10.1021/jacs.5b08500

Reference yield: 67.0%

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 79060-88-1
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

: 5259-72-3,10060-40-9,111-78-4
cyclo-octa-1,5-diene

: 404573-66-6
bis(1,5-cyclooctadiene)rhodium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Guidance literature:: In dichloromethane; inert atm.; to a soln. of Rh-complex in CH2Cl2 was added solid Na-compound, then 1,5-cyclooctadiene, the suspn. was stirred for 30 min at room temp.; filtered, evapd., recrystd. from CH2Cl2-hexane; elem. anal.;
DOI:10.1021/om050010e