(S)-(-)-tert-Butyl 2-(N-benzyl-N-benzyloxycarbamoylmethyl)heptanoate

Base Information

Chemical Name:(S)-(-)-tert-Butyl 2-(N-benzyl-N-benzyloxycarbamoylmethyl)heptanoate
CAS No.:149126-72-7
Molecular Formula:C₂₇H₃₇NO₄
Molecular Weight:439.595
Hs Code.:

Synonyms:(S)-(-)-tert-Butyl 2-(N-benzyl-N-benzyloxycarbamoylmethyl)heptanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-(-)-tert-Butyl 2-(N-benzyl-N-benzyloxycarbamoylmethyl)heptanoate

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Technology Process of (S)-(-)-tert-Butyl 2-(N-benzyl-N-benzyloxycarbamoylmethyl)heptanoate

There total 6 articles about (S)-(-)-tert-Butyl 2-(N-benzyl-N-benzyloxycarbamoylmethyl)heptanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: (S,S)-(+)-(η5-C5H5)Fe(CO)(PPh3)COCH2CH(C5H11)CO2CH3

: 4383-24-8
N,O-dibenzylhydroxylamine

: 149126-72-7
(S)-(-)-tert-Butyl 2-(N-benzyl-N-benzyloxycarbamoylmethyl)heptanoate

Guidance literature:: With N-Bromosuccinimide; In dichloromethane; addn. of N-bromo succinimid to a soln. of Fe-complex in CH2Cl2 at -40°C under N2, stirring for 30 min, addn. of a soln. of N,O-dibenzylhydroxylamine in CH2Cl2, stirring for 30 min, warming to 20°C, stirring for further 2 h; evapn. of solvent, column chromy. on flash silica with ether/light petroleum, rechromy. using ether/light petroleum to give ester, elem. anal.;
DOI:10.1039/P19930000459

Reference yield:

: 17146-21-3
O-(benzyl)benzaldoxime

: 149126-72-7
(S)-(-)-tert-Butyl 2-(N-benzyl-N-benzyloxycarbamoylmethyl)heptanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 79 percent / NaBH₃CN, conc. HCl / methanol / 0.5 h

With hydrogenchloride; sodium cyanoborohydride; In methanol;
DOI:10.1039/P19930000459

Reference yield:

: 100-39-0
benzyl bromide

: 149126-72-7
(S)-(-)-tert-Butyl 2-(N-benzyl-N-benzyloxycarbamoylmethyl)heptanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / NaH, Bu₄NI / tetrahydrofuran

2: 79 percent / NaBH₃CN, conc. HCl / methanol / 0.5 h

With hydrogenchloride; tetra-(n-butyl)ammonium iodide; sodium hydride; sodium cyanoborohydride; In tetrahydrofuran; methanol;
DOI:10.1039/P19930000459