tert-butyl-(R)-(1-(4-methoxybenzyloxy)pent-4-en-2-yloxy)dimethylsilane

Base Information

Chemical Name:tert-butyl-(R)-(1-(4-methoxybenzyloxy)pent-4-en-2-yloxy)dimethylsilane
CAS No.:1012367-41-7
Molecular Formula:C₁₉H₃₂O₃Si
Molecular Weight:336.547
Hs Code.:

Synonyms:tert-butyl-(R)-(1-(4-methoxybenzyloxy)pent-4-en-2-yloxy)dimethylsilane

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Chemical Property of tert-butyl-(R)-(1-(4-methoxybenzyloxy)pent-4-en-2-yloxy)dimethylsilane

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Technology Process of tert-butyl-(R)-(1-(4-methoxybenzyloxy)pent-4-en-2-yloxy)dimethylsilane

There total 3 articles about tert-butyl-(R)-(1-(4-methoxybenzyloxy)pent-4-en-2-yloxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 194342-84-2
(R)-1-[(4-methoxybenzyl)oxy]pent-4-en-2-ol

: 1012367-41-7
tert-butyl-(R)-(1-(4-methoxybenzyloxy)pent-4-en-2-yloxy)dimethylsilane

Guidance literature:: With 1H-imidazole; In dichloromethane; at 0 - 20 ℃; for 16h; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.0c02190

Reference yield:

: 80910-01-6,108836-41-5,144069-33-0,134733-19-0
(R)-2-(((4-methoxybenzyl)oxy)methyl)oxirane

: 1012367-41-7
tert-butyl-(R)-(1-(4-methoxybenzyloxy)pent-4-en-2-yloxy)dimethylsilane

Guidance literature:: Multi-step reaction with 2 steps

1: copper(l) cyanide / tetrahydrofuran / 4 h / -78 - -40 °C

2: dmap; 1H-imidazole / dichloromethane / 3 h / 0 - 20 °C

With 1H-imidazole; dmap; copper(l) cyanide; In tetrahydrofuran; dichloromethane;
DOI:10.1055/s-0033-1338952

Reference yield:

: 824-94-2
p-methoxybenzyl chloride

: 1012367-41-7
tert-butyl-(R)-(1-(4-methoxybenzyloxy)pent-4-en-2-yloxy)dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.42 h / 0 °C / Schlenk technique; Inert atmosphere

1.2: 16 h / 0 - 20 °C / Schlenk technique; Inert atmosphere

2.1: copper(l) iodide / tetrahydrofuran / 3 h / -78 °C / Schlenk technique; Inert atmosphere

3.1: 1H-imidazole / dichloromethane / 16 h / 0 - 20 °C / Schlenk technique; Inert atmosphere

With 1H-imidazole; copper(l) iodide; sodium hydride; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1021/acs.orglett.0c02190