meso-(tetrakis(2,6-dibromophenyl)porphinato)chromium(III)chloride

Base Information

• Chemical Name: meso-(tetrakis(2,6-dibromophenyl)porphinato)chromium(III)chloride
• CAS No.: 134818-43-2
• Molecular Formula: C₄₄H₂₀Br₈ClCrN₄
• Molecular Weight: 1331.35
• Mol file: 134818-43-2.mol

Synonyms:meso-(tetrakis(2,6-dibromophenyl)porphinato)chromium(III)chloride

Chemical Property of meso-(tetrakis(2,6-dibromophenyl)porphinato)chromium(III)chloride

Chemical Property:

Purity/Quality:

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Technology Process of meso-(tetrakis(2,6-dibromophenyl)porphinato)chromium(III)chloride

There total 1 articles about meso-(tetrakis(2,6-dibromophenyl)porphinato)chromium(III)chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chromium dichloride + 5,10,15,20-tetrakis(2,6-dibromophenyl)porphyrin → meso-(tetrakis(2,6-dibromophenyl)porphinato)chromium(III)chloride (134818-43-2)

Guidance literature:

In N,N-dimethyl-formamide; toluene; chromy;;

Reference yield: 50.0%

meso-(tetrakis(2,6-dibromophenyl)porphinato)chromium(III)chloride (134818-43-2) → oxo(meso-tetrakis(2,6-dibromophenyl)porphinato)chromium(IV) (134818-46-5)

Guidance literature:

With IBDA; In dichloromethane; chromy. after 15 min (basic alumina (activity V), purified CH2Cl2); evaporation to dryness; recrystallization in benzene-pentane:;

Reference yield: 20.2%

meso-(tetrakis(2,6-dibromophenyl)porphinato)chromium(III)chloride (134818-43-2) + [bis(acetoxy)iodo]benzene (3240-34-4) → oxo(meso-tetrakis(2,6-dibromophenyl)porphinato)chromium(IV) (134818-46-5)

Guidance literature:

In dichloromethane; react. of Cr complex and iodobenzene diacetate for 15 min; chromy. (alumina, activity V), red band was evapd. to dryness; recrystn. from benzene/pentane;

DOI:10.1021/ja00195a060

Downstream raw materials:

oxo(meso-tetrakis(2,6-dibromophenyl)porphinato)chromium(IV)