(η6-C6Et6)Ta(2,6-diisopropylphenoxide)2

Base Information

• Chemical Name: (η6-C6Et6)Ta(2,6-diisopropylphenoxide)2
• CAS No.: 125820-42-0
• Molecular Formula: C₄₂H₆₄O₂Ta
• Molecular Weight: 781.917
• Mol file: 125820-42-0.mol

Synonyms:(η6-C6Et6)Ta(2,6-diisopropylphenoxide)2

Chemical Property of (η6-C6Et6)Ta(2,6-diisopropylphenoxide)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η6-C6Et6)Ta(2,6-diisopropylphenoxide)2

There total 2 articles about (η6-C6Et6)Ta(2,6-diisopropylphenoxide)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

(η6-C6Et6)Ta(2,6-diisopropylphenoxide)2Cl (110551-63-8) → (η6-C6Et6)Ta(2,6-diisopropylphenoxide)2 (125820-42-0)

Guidance literature:

With Na#Hg; In diethyl ether; byproducts: NaCl; react. at room temp. for 16 h, 1.5 equiv. sodium amalgam; elem. anal.;

DOI:10.1039/c39890000664

Reference yield: 32.0%

Ta(OC6H3(CH(CH3)2)2)2Cl3(C2H5OC2H5) (125950-54-1) + hex-3-yne (928-49-4) → (η6-C6Et6)Ta(2,6-diisopropylphenoxide)2 (125820-42-0)

Guidance literature:

With NaHg amalgam; In diethyl ether; (N2), cooled to -40°C under stirring, added C6H10 and NaHg amalgam, stirred at room temp. for 1 h; filtered through Celite, filtrate pumped to dryness, dissolved in pentane, cooled to -40°C, filtered off, washed with cold pentane, dried in vac.; elem. anal., IR, NMR;

Reference yield: 50.0%

(η6-C6Et6)Ta(2,6-diisopropylphenoxide)2 (125820-42-0) → (η6-C6Et6)Ta(2,6-diisopropylphenoxide)2Cl (110551-63-8)

Guidance literature:

With CH₂Cl₂; In diethyl ether;

DOI:10.1039/c39890000664

upstream raw materials:

(η6-C6Et6)Ta(2,6-diisopropylphenoxide)2Cl

Ta(OC₆H₃(CH(CH₃)2)2)2Cl₃(C₂H₅OC₂H₅)

hex-3-yne

Downstream raw materials:

(η6-C6Et6)Ta(2,6-diisopropylphenoxide)2Br

(η6-C6Et6)Ta(2,6-diisopropylphenoxide)2Cl

(C₆(C₂H₅)6)Ta(C₆H₃O(CH(CH₃)2)2)2I