cis-Os(bpy)2(CO₃)*2H₂O

Base Information

• Chemical Name: cis-Os(bpy)2(CO₃)*2H₂O
• CAS No.: 81831-23-4
• Molecular Formula: C₂₁H₁₆N₄O₃Os*H₂O
• Molecular Weight: 598.614
• Mol file: 81831-23-4.mol

Synonyms:cis-Os(bpy)2(CO₃)*2H₂O

Chemical Property of cis-Os(bpy)2(CO₃)*2H₂O

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-Os(bpy)2(CO₃)*2H₂O

There total 1 articles about cis-Os(bpy)2(CO₃)*2H₂O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

cis-[bis(2,2'-bipyridine)dichloridoosmium(II)] (79982-56-2) → {Os(2,2'-bipyridine)2CO3*H2O (81831-23-4)

Guidance literature:

With sodium carbonate; In water; soln. of Os-complex and Na2CO3 heated for 2 h (reflux, N2), cooled at room temp., added Na2CO3, heated again; cooled, crystd. (H2O), filtered, washed (H2O, Et2O), dried (vac. at 70°C for 8 h), elem. anal.;

Reference yield: 60.0%

ammonium hexafluorophosphate + cis-Os(bpy)2(CO3)*2H2O (81831-23-4) + N-(pyridin-4-yl)cinnamamide (85649-70-3) → cis-(Os(bpy)2(p-cinn)2)(PF6)2 (85717-52-8)

Guidance literature:

With trifluoroacetic acid; In butan-1-ol; deoxygenated suspn. cis-Os(bpy)2(CO3)*2H2O in n-butanol plus CF3COOH gently heated with stirring for 30 min, 10-fold excess p-cinn added and react. mixt. refluxed for 4 h, aq. soln. NH4PF6 added; ppt. collected and chromed. (1:1 toluene/CH3CN), complex repptd. from CH2Cl2 into ether, filtered and dried;

Reference yield: 30.0%

4-vinylpyridine (100-43-6,329041-72-7) + ammonium hexafluorophosphate + cis-Os(bpy)2(CO3)*2H2O (81831-23-4) → cis-(Os(bpy)2(vpy)2)(PF6)2 (85661-63-8)

Guidance literature:

With trifluoroacetic acid; In butan-1-ol; deoxygenated suspn. cis-Os(bpy)2(CO3)*2H2O in n-butanol plus CF3COOH gently heated with stirring for 30 min, excess vpy added and react. mixt. refluxed for 4 h, aq. soln. NH4PF6 added; ppt. collected and chromed. (1:1 toluene/CH3CN), complex repptd. from CH2Cl2 into ether, filtered and dried; elem. anal.;

upstream raw materials:

cis-[bis(2,2'-bipyridine)dichloridoosmium(II)]

Downstream raw materials:

cis-(Os(bpy)2(vpy)2)(PF₆)2

cis-(Os(bpy)2(p-cinn)2)(PF₆)2