5,10,15-((1,3,5-benzenetriyltriacetyl)tris(α,α,α-o-aminophenyl))-20-((α-o-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)(carbonyl)

Base Information

Chemical Name:5,10,15-((1,3,5-benzenetriyltriacetyl)tris(α,α,α-o-aminophenyl))-20-((α-o-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)(carbonyl)
CAS No.:78694-32-3
Molecular Formula:C₆₆H₅₂FeN₁₀O₅
Molecular Weight:1121.05
Hs Code.:

Synonyms:5,10,15-((1,3,5-benzenetriyltriacetyl)tris(α,α,α-o-aminophenyl))-20-((α-o-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)(carbonyl)

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Chemical Property of 5,10,15-((1,3,5-benzenetriyltriacetyl)tris(α,α,α-o-aminophenyl))-20-((α-o-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)(carbonyl)

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Technology Process of 5,10,15-((1,3,5-benzenetriyltriacetyl)tris(α,α,α-o-aminophenyl))-20-((α-o-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)(carbonyl)

There total 2 articles about 5,10,15-((1,3,5-benzenetriyltriacetyl)tris(α,α,α-o-aminophenyl))-20-((α-o-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)(carbonyl) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 250253-20-4,77338-87-5
5,10,15-((1,3,5-benzenetriyltriacetyl)tris(α,α,α-o-aminophenyl))-20-((α-o-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)

: 78694-32-3
5,10,15-((1,3,5-benzenetriyltriacetyl)tris(α,α,α-o-aminophenyl))-20-((α-o-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)(carbonyl)

Guidance literature:: With carbon monoxide; In toluene; Irradiation (UV/VIS); 25°C; flash photolysis; concn. of CO = 3E-4 to 1E-3 M; concn. of1-methylimidazole = 1-2 M; Kinetics;
DOI:10.1021/ja00348a019

Reference yield:

: 616-47-7
1-methyl-1H-imidazole

: 77351-48-5
Fe(C₂₀N₄H₈(C₆H₃(CH₂CONHC₆H₄)3)(C₆H₄NHCOC(CH₃)3))

: 78694-32-3
Fe(C₂₀N₄H₈(C₆H₃(CH₂CONHC₆H₄)3)(C₆H₄NHCOC(CH₃)3))(CO)(C₃N₂H₃CH₃)

Guidance literature:: With carbon monoxide; In dichloromethane; a soln. of the Fe complex and the imidazole in CH2Cl2 was frozen in liq. N2, thawing unter 1 atm of CO gas; detected by UV and Raman spectroscopy;
DOI:10.1021/ja00080a019

Reference yield:

: 78694-32-3
5,10,15-((1,3,5-benzenetriyltriacetyl)tris(α,α,α-o-aminophenyl))-20-((α-o-pivalamidophenyl)porphyrinato)iron(II)(1-methylimidazole)(carbonyl)

: 77351-48-5
5,10,15-((1,3,5-benzenetriyltriacetyl)tris(α,α,α-o-aminophenyl))-20-((α-o-pivalamidophenyl)porphyrinato)iron(II)

Guidance literature:: In toluene; Irradiation (UV/VIS); 25°C; flash photolysis; low concentrations of CO an 1-methylimidazole; Kinetics;
DOI:10.1021/ja00348a019