1,1'-dilithioferrocene

Base Information

• Chemical Name: 1,1'-dilithioferrocene
• CAS No.: 33272-09-2
• Molecular Formula: C₁₀H₈FeLi₂
• Molecular Weight: 197.903
• Mol file: 33272-09-2.mol

Synonyms:1,1'-dilithioferrocene

Chemical Property of 1,1'-dilithioferrocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1'-dilithioferrocene

There total 4 articles about 1,1'-dilithioferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

ferrocene (102-54-5,55404-68-7) + n-butyllithium (109-72-8,29786-93-4) → lithiumferrocene (1271-15-4) + 1,1'-dilithioferrocene (33272-09-2)

Guidance literature:

In diethyl ether; 5 h, boiling;

Reference yield:

ferrocene (102-54-5,55404-68-7) + n-butyllithium (109-72-8,29786-93-4) + N,N,N,N,-tetramethylethylenediamine (110-18-9) → lithiumferrocene (1271-15-4) + 1,1'-dilithioferrocene (33272-09-2)

Guidance literature:

In hexane;

DOI:10.1016/S0022-328X(00)80241-7 DOI:10.1016/S0022-328X(00)81725-8

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + 1,1'-diiodoferrocene (12145-93-6) → lithiumferrocene (1271-15-4) + 1,1'-dilithioferrocene (33272-09-2)

Guidance literature:

DOI:10.1016/S0040-4039(01)88600-7

upstream raw materials:

ferrocene

n-butyllithium

N,N,N,N,-tetramethylethylenediamine

1,1'-diiodoferrocene

Downstream raw materials:

1,1'-bis-(diphenylphosphino)ferrocene