(+)-(Ss,5S,7S)-N-[7-(benzyloxy)dodec-1-en-5-yl]-2-methylpropane-2-sulfinamide

Base Information

Chemical Name:(+)-(Ss,5S,7S)-N-[7-(benzyloxy)dodec-1-en-5-yl]-2-methylpropane-2-sulfinamide
CAS No.:1377322-08-1
Molecular Formula:C₂₃H₃₉NO₂S
Molecular Weight:393.634
Hs Code.:

Synonyms:(+)-(Ss,5S,7S)-N-[7-(benzyloxy)dodec-1-en-5-yl]-2-methylpropane-2-sulfinamide

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Chemical Property of (+)-(Ss,5S,7S)-N-[7-(benzyloxy)dodec-1-en-5-yl]-2-methylpropane-2-sulfinamide

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Technology Process of (+)-(Ss,5S,7S)-N-[7-(benzyloxy)dodec-1-en-5-yl]-2-methylpropane-2-sulfinamide

There total 2 articles about (+)-(Ss,5S,7S)-N-[7-(benzyloxy)dodec-1-en-5-yl]-2-methylpropane-2-sulfinamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 1377322-00-3
(+)-(Ss,5S,7S)-N-(7-hydroxydodec-1-en-5-yl)-2-methylpropane-2-sulfinamide

: 100-39-0
benzyl bromide

: 1377322-08-1
(+)-(Ss,5S,7S)-N-[7-(benzyloxy)dodec-1-en-5-yl]-2-methylpropane-2-sulfinamide

Guidance literature:: (+)-(Ss,5S,7S)-N-(7-hydroxydodec-1-en-5-yl)-2-methylpropane-2-sulfinamide; With sodium hydride; In tetrahydrofuran; mineral oil; at 0 ℃; for 0.0833333h; Inert atmosphere;

benzyl bromide; In tetrahydrofuran; mineral oil; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1002/anie.201201001

Reference yield:

: 2100-17-6
4-pentenal

: 1377322-08-1
(+)-(Ss,5S,7S)-N-[7-(benzyloxy)dodec-1-en-5-yl]-2-methylpropane-2-sulfinamide

Guidance literature:: Multi-step reaction with 4 steps

1.1: titanium(IV) tetraethanolate / tetrahydrofuran / 0.08 h / 20 °C / Inert atmosphere

1.2: 14 h / 20 °C / Inert atmosphere

2.1: potassium hexamethylsilazane / diethyl ether / 1 h / -78 °C / Inert atmosphere

2.2: 2 h / -78 °C / Inert atmosphere

3.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / tetrahydrofuran / 0 °C / Inert atmosphere

4.1: sodium hydride / tetrahydrofuran; mineral oil / 0.08 h / 0 °C / Inert atmosphere

4.2: 0 - 20 °C / Inert atmosphere

With titanium(IV) tetraethanolate; sodium tetrahydroborate; cerium(III) chloride heptahydrate; potassium hexamethylsilazane; sodium hydride; In tetrahydrofuran; diethyl ether; mineral oil; 2.1: Mannich reaction;
DOI:10.1002/anie.201201001