dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin

Base Information

• Chemical Name: dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin
• CAS No.: 796104-34-2
• Molecular Formula: C₄₄H₂₀Cl₁₀N₄Ru
• Molecular Weight: 1060.27
• Mol file: 796104-34-2.mol

Synonyms:dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin

Chemical Property of dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin

There total 2 articles about dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)(dioxo)ruthenium(VI) (142718-07-8) → dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin (796104-34-2)

Guidance literature:

With chloro-trimethyl-silane; In dichloromethane; for 0.166667h;

DOI:10.1002/adsc.201000455

Reference yield:

chloro-trimethyl-silane (75-77-4) + (5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)(dioxo)ruthenium(VI) (142718-07-8) → dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin (796104-34-2)

Guidance literature:

In dichloromethane; for 2h; Inert atmosphere;

DOI:10.1021/jacs.8b04470

Reference yield:

dichlororuthenium(IV) meso-tetrakis(2,6-dichlorophenyl)porphyrin (796104-34-2) → (5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)(dioxo)ruthenium(VI) (142718-07-8)

Guidance literature:

With air; sodium hydrogencarbonate; In chloroform-d1; water; soln. of Ru porphyrin in CDCl3 mixed with aq. NaHCO3 (10 equiv.) at roomtemp., mixt. exposed to air for 12 h; detected by NMR spectroscopy;

DOI:10.1002/anie.200801500

upstream raw materials:

(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)(dioxo)ruthenium(VI)

chloro-trimethyl-silane

Downstream raw materials:

(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)(dioxo)ruthenium(VI)