[((N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3)Ag₃(triflate)3]-acetonitrile(1/1)

Base Information

• Chemical Name: [((N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3)Ag₃(triflate)3]-acetonitrile(1/1)
• CAS No.: 852235-53-1
• Molecular Formula: C₂H₃N*C₃₆H₃₆Ag₃F₉N₃O₉RhS₃
• Molecular Weight: 1389.44
• Mol file: 852235-53-1.mol

Synonyms:[((N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3)Ag₃(triflate)3]-acetonitrile(1/1)

Chemical Property of [((N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3)Ag₃(triflate)3]-acetonitrile(1/1)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [((N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3)Ag₃(triflate)3]-acetonitrile(1/1)

There total 2 articles about [((N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3)Ag₃(triflate)3]-acetonitrile(1/1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

(N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3 (852235-50-8) + silver trifluoromethanesulfonate (2923-28-6) + acetonitrile (75-05-8,26809-02-9) → [((N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3)Ag3(triflate)3]-acetonitrile(1/1) (852235-53-1)

Guidance literature:

In acetonitrile; (NMe)3C6H12Rh(CCC6H5)3 reacted with Ag(O3SCF3) in acetonitrile; XRD;

DOI:10.1021/ja050154k

Reference yield:

trichloro(N,N',N''-trimethyl-1,4,7-trazacyclononane)rhodium(III) (140175-14-0) + lithium phenylacetylide (4440-01-1) → [((N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3)Ag3(triflate)3]-acetonitrile(1/1) (852235-53-1)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: acetonitrile

In tetrahydrofuran; acetonitrile;

DOI:10.1021/ja050154k

upstream raw materials:

(N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3

silver trifluoromethanesulfonate

acetonitrile

trichloro(N,N',N''-trimethyl-1,4,7-trazacyclononane)rhodium(III)