(N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3

Base Information

• Chemical Name: (N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3
• CAS No.: 852235-50-8
• Molecular Formula: C₃₃H₃₆N₃Rh
• Molecular Weight: 577.574
• Mol file: 852235-50-8.mol

Synonyms:(N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3

Chemical Property of (N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3

There total 1 articles about (N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

trichloro(N,N',N''-trimethyl-1,4,7-trazacyclononane)rhodium(III) (140175-14-0) + lithium phenylacetylide (4440-01-1) → (N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3 (852235-50-8)

Guidance literature:

In tetrahydrofuran; (NMe)3C6H12RhCl3 reacted with excess PhCCLi in THF at -78°C; XRD;

DOI:10.1021/ja050154k

Reference yield: 97.0%

silver tetrafluoroborate (14104-20-2) + (N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3 (852235-50-8) → [((N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3)2Ag2](tetrafluoroborate)2

Guidance literature:

In acetonitrile; (NMe)3C6H12Rh(CCC6H5)3 reacted with excess AgBF4 in acetonitrile; XRD;

DOI:10.1021/ja050154k

Reference yield: 88.0%

(N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3 (852235-50-8) + silver trifluoromethanesulfonate (2923-28-6) + acetonitrile (75-05-8,26809-02-9) → [((N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3)Ag3(triflate)3]-acetonitrile(1/1) (852235-53-1)

Guidance literature:

In acetonitrile; (NMe)3C6H12Rh(CCC6H5)3 reacted with Ag(O3SCF3) in acetonitrile; XRD;

DOI:10.1021/ja050154k

upstream raw materials:

trichloro(N,N',N''-trimethyl-1,4,7-trazacyclononane)rhodium(III)

lithium phenylacetylide

Downstream raw materials:

[((N,N',N''-trimethyl-1,4,7-triazacyclononane)Rh(phenylacetylide)3)Ag₃(triflate)3]-acetonitrile(1/1)