(Co(II))2(gable porphyrin)

Base Information

• Chemical Name: (Co(II))2(gable porphyrin)
• CAS No.: 85318-78-1
• Molecular Formula: C₈₂H₅₀Co₂N₈
• Molecular Weight: 1265.34
• Mol file: 85318-78-1.mol

Synonyms:(Co(II))2(gable porphyrin)

Chemical Property of (Co(II))2(gable porphyrin)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Co(II))2(gable porphyrin)

There total 1 articles about (Co(II))2(gable porphyrin) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

1,3-bis(5'-(10',15',20'-triphenylporphinyl))benzene + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) → (Co(II))2(gable porphyrin) (85318-78-1)

Guidance literature:

In N,N-dimethyl-formamide; a mixt. of porphyrine and dry DMF was heated to reflux until the porphyrrine dissolved, anhyd. CoCl2 was added with stirring under Ar, reactionwas complete in 1.5 h (UV/Vis control); cooled to room temp., H2O was added, ppt. was collected by suction filtration, washed with H2O, MeOH, dried in vacuo, dissolved in THF, chromd.on a SiO2 column (eluent THF), recrystd. from THF-hexane;

DOI:10.1021/ja00300a019

Reference yield:

1-methyl-1H-imidazole (616-47-7) + (Co(II))2(gable porphyrin) (85318-78-1) → (Co(II))2(gable porphyrin)(N-methylimidazole) (85335-08-6)

Guidance literature:

In N,N-dimethyl-formamide; -20°C;

Reference yield:

1,1'-bis(imidazolyl)methane (84661-56-3) + (Co(II))2(gable porphyrin) (85318-78-1) → (Co(II))2(gable porphyrin)(diimidazolylmethane) (85318-80-5)

Guidance literature:

In N,N-dimethyl-formamide; -20°C;

upstream raw materials:

cobalt(II) chloride

Downstream raw materials:

(Co(II))2(gable porphyrin)(N-methylimidazole)

(Co(II))2(gable porphyrin)(diimidazolylmethane)