(2R,3S,4S,5R,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6-dicyclohexylmethylsulfanyl-tetrahydro-pyran-3,4,5-triol

Base Information

Chemical Name:(2R,3S,4S,5R,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6-dicyclohexylmethylsulfanyl-tetrahydro-pyran-3,4,5-triol
CAS No.:197164-77-5
Molecular Formula:C₂₅H₄₈O₅SSi
Molecular Weight:488.805
Hs Code.:

Synonyms:(2R,3S,4S,5R,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6-dicyclohexylmethylsulfanyl-tetrahydro-pyran-3,4,5-triol

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Chemical Property of (2R,3S,4S,5R,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6-dicyclohexylmethylsulfanyl-tetrahydro-pyran-3,4,5-triol

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Technology Process of (2R,3S,4S,5R,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6-dicyclohexylmethylsulfanyl-tetrahydro-pyran-3,4,5-triol

There total 4 articles about (2R,3S,4S,5R,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6-dicyclohexylmethylsulfanyl-tetrahydro-pyran-3,4,5-triol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Dicyclohexyl-methanethiol

: 197164-77-5
(2R,3S,4S,5R,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6-dicyclohexylmethylsulfanyl-tetrahydro-pyran-3,4,5-triol

Guidance literature:: Multi-step reaction with 3 steps

1: 18 percent / TMSOTf / CH₂Cl₂ / 16 h / Ambient temperature

2: NaOMe / CH₂Cl₂; methanol / 3 h

3: pyridine / 18 h / Ambient temperature

With trimethylsilyl trifluoromethanesulfonate; sodium methylate; In pyridine; methanol; dichloromethane;
DOI:10.1021/jo971233k

Reference yield:

: 171503-67-6
Acetic acid (2R,3R,4S,5R,6S)-3,5-diacetoxy-2-acetoxymethyl-6-dicyclohexylmethylsulfanyl-tetrahydro-pyran-4-yl ester

: 197164-77-5
(2R,3S,4S,5R,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6-dicyclohexylmethylsulfanyl-tetrahydro-pyran-3,4,5-triol

Guidance literature:: Multi-step reaction with 2 steps

1: NaOMe / CH₂Cl₂; methanol / 3 h

2: pyridine / 18 h / Ambient temperature

With sodium methylate; In pyridine; methanol; dichloromethane;
DOI:10.1021/jo971233k

Reference yield:

: 604-69-3
β-D-glucose pentaacetate

: 197164-77-5
(2R,3S,4S,5R,6S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-6-dicyclohexylmethylsulfanyl-tetrahydro-pyran-3,4,5-triol

Guidance literature:: Multi-step reaction with 3 steps

1: 18 percent / TMSOTf / CH₂Cl₂ / 16 h / Ambient temperature

2: NaOMe / CH₂Cl₂; methanol / 3 h

3: pyridine / 18 h / Ambient temperature

With trimethylsilyl trifluoromethanesulfonate; sodium methylate; In pyridine; methanol; dichloromethane;
DOI:10.1021/jo971233k