{5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-ethynylphenyl)porphyrinato(2-)-κN²¹,κN²²,κN²³,κN²⁴}zinc(II)

Base Information

• Chemical Name: {5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-ethynylphenyl)porphyrinato(2-)-κN²¹,κN²²,κN²³,κN²⁴}zinc(II)
• CAS No.: 1200934-79-7
• Molecular Formula: C₆₄H₆₀N₄Zn
• Molecular Weight: 950.597

Synonyms:{5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-ethynylphenyl)porphyrinato(2-)-κN²¹,κN²²,κN²³,κN²⁴}zinc(II)

Chemical Property of {5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-ethynylphenyl)porphyrinato(2-)-κN²¹,κN²²,κN²³,κN²⁴}zinc(II)

Chemical Property:

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Technology Process of {5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-ethynylphenyl)porphyrinato(2-)-κN²¹,κN²²,κN²³,κN²⁴}zinc(II)

There total 2 articles about {5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-ethynylphenyl)porphyrinato(2-)-κN²¹,κN²²,κN²³,κN²⁴}zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

(5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis{4-[(triisopropylsilyl)-ethynyl]phenyl}porphyrinato(2-)-κN21,κN22,κN23,κN24)zinc(II) → {5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-ethynylphenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24}zinc(II) (1200934-79-7)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 25 ℃; for 1h; Inert atmosphere;

DOI:10.1002/ejoc.201402634

Reference yield: 23.0%

pyrrole (109-97-7,30604-81-0) + 3,5-Di-tert-butylbenzaldehyde (17610-00-3) + 4-[(trimethylsilyl)ethynyl]bezaldehyde (77123-57-0) → {5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-ethynylphenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24}zinc(II) (1200934-79-7) + C64H60N4Zn (1200934-78-6)

Guidance literature:

pyrrole; 3,5-Di-tert-butylbenzaldehyde; 4-[(trimethylsilyl)ethynyl]bezaldehyde; With boron trifluoride diethyl etherate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In chloroform; at 20 ℃; for 2h;

With potassium carbonate; In tetrahydrofuran; methanol; at 20 ℃; for 2h;

With zinc diacetate; In methanol; chloroform; at 20 ℃; for 2h;

DOI:10.1021/nl9029994

Reference yield: 84.0%

10-(4-azidomethylphenyl)-5,15-dimesitylcorrole + {5,15-bis[3,5-di(tert-butyl)phenyl]-10,20-bis(4-ethynylphenyl)porphyrinato(2-)-κN21,κN22,κN23,κN24}zinc(II) (1200934-79-7) + copper(II) sulfate (7758-99-8) → C152H132Cu2N18Zn

Guidance literature:

With ascorbic acid;

DOI:10.1039/c9cc09681g

upstream raw materials:

pyrrole

3,5-Di-tert-butylbenzaldehyde

4-[(trimethylsilyl)ethynyl]bezaldehyde

Downstream raw materials:

[Zn(C₂₀H₈N₄(C₆H₄C₂C₅H₄N)2(C₆H₃(C(CH₃)3)2)2)]

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