[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]ClO₄

Base Information

Chemical Name:[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]ClO₄
CAS No.:494831-11-7
Molecular Formula:C₄₁H₄₂NO₂P₂Pd*ClO₄
Molecular Weight:848.608
Hs Code.:

[Pd(2,3-(MeO)2C<sub>6</sub>H<sub>2</sub>CH=N(Cy)-C<sub>6</sub>,N)((Ph<sub>2</sub>P)2CCH<sub>2</sub>-P,P')]ClO<sub>4</sub>

Synonyms:[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]ClO₄

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Chemical Property of [Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]ClO₄

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Technology Process of [Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]ClO₄

There total 1 articles about [Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 494831-06-0
[Pd(2,3-(MeO)2C6H2CH=N(Cy)-C6,N)(μ-Cl)]2

: sodium perchlorate

: 84494-89-3
1,1-bis-(diphenylphosphino)ethene

: 494831-11-7
[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]ClO₄

Guidance literature:: In water; acetone; under Ar, 2 equiv. of P-compd. was added to Me2CO soln. of Pd-compd., stirring at room temp. for 30 min, NaClO4 was added, stirring for 30 min, H2O was added, stirring for 12 h; ppt. was filtered off, washed twice with water, dried in vac. over CaCl2, recrystn. from CHCl3 by gaseous Et2O diffusion;
DOI:10.1039/b203864a

Reference yield: 77.0%

: 494831-11-7
[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]ClO₄

: 105-53-3
diethyl malonate

: 494831-50-4
[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CHCH₂CH(COOEt)(COOEt)-P,P')]ClO₄

Guidance literature:: sodium carbonate; In chloroform; under Ar, 2 equiv. of the ester, heating in dry CHCl3 at 45 °C for 15 h in the presence of anhyd. Na2CO3; soln. was cooled to room temp., filtered through Celite, evapd. in vac.,residue was triturated with Et2O, filtered off, washed with cold Et2O, dried in vac.;
DOI:10.1039/b203864a

Reference yield: 37.0%

: 494831-11-7
[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CCH₂-P,P')]ClO₄

: 1540-34-7
3-ethyl-2,4-pentanedione

: 494831-53-7
[Pd(2,3-(MeO)2C₆H₂CH=N(Cy)-C₆,N)((Ph₂P)2CHCH₂C(Et)(COMe)(COMe)-P,P')]ClO₄

Guidance literature:: sodium carbonate; In chloroform; under Ar, 2 equiv. of the ester, heating in dry CHCl3 at 45 °C for 20 h in the presence of anhyd. Na2CO3;; soln. was cooled to room temp., filtered through Celite, evapd. in vac.,residue was triturated with Et2O, filtered off, washed with cold Et2O, dried in vac.; neither recrystn. nor chromy. led to pure product;
DOI:10.1039/b203864a