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[(PhB(CH2PPh2)3)RhH(acetonitrile)2]BF4

Base Information
  • Chemical Name:[(PhB(CH2PPh2)3)RhH(acetonitrile)2]BF4
  • CAS No.:1359870-01-1
  • Molecular Formula:BF4*C49H48BN2P3Rh
  • Molecular Weight:958.376
  • Hs Code.:
[(PhB(CH<sub>2</sub>PPh<sub>2</sub>)3)RhH(acetonitrile)2]BF<sub>4</sub>

Synonyms:[(PhB(CH2PPh2)3)RhH(acetonitrile)2]BF4

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Chemical Property of [(PhB(CH2PPh2)3)RhH(acetonitrile)2]BF4
Chemical Property:
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Technology Process of [(PhB(CH2PPh2)3)RhH(acetonitrile)2]BF4

There total 4 articles about [(PhB(CH2PPh2)3)RhH(acetonitrile)2]BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
In dichloromethane; acetonitrile; (Ar, Schlenk technique); addn. of etherate of HBF4 and CH3CN to rhodium compd. in CH2Cl2 at -50°C, warming to room temp.; concg., layering with hexane, filtration, washing with hexane, drying invac., elem. anal.;
DOI:10.1021/om201129j
Guidance literature:
at -30 - 30 ℃; Equilibrium constant; Inert atmosphere; Schlenk technique; Glovebox;
DOI:10.1021/acs.organomet.6b00036
Guidance literature:
Multi-step reaction with 2 steps
1: acetonitrile
2: acetonitrile
In acetonitrile;
DOI:10.1021/om201129j
upstream raw materials:

tetrafluoroboric acid diethyl ether

[Rh(PhBP3)(H)2(NCMe)]

acetonitrile

Downstream raw materials:

acetonitrile

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