(E)-N'-(1-(2-((Z)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(methylthio)vinyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide

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Chemical Name:(E)-N'-(1-(2-((Z)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(methylthio)vinyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide
CAS No.:1359978-77-0
Molecular Formula:C₂₆H₂₂F₆N₂O₂S₂
Molecular Weight:572.595
Hs Code.:

Synonyms:(E)-N'-(1-(2-((Z)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(methylthio)vinyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide

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Chemical Property of (E)-N'-(1-(2-((Z)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(methylthio)vinyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide

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Technology Process of (E)-N'-(1-(2-((Z)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(methylthio)vinyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide

There total 3 articles about (E)-N'-(1-(2-((Z)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(methylthio)vinyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 1359978-79-2
(Z)-1-(2-(2-(3,5-bis(trifluoromethyl)phenyl)-2-(methylthio)vinyl)phenyl)ethanone

: 1576-35-8
toluene-4-sulfonic acid hydrazide

: 1359978-77-0
(E)-N'-(1-(2-((Z)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(methylthio)vinyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide

Guidance literature:: With acetic acid; In ethanol; at 20 ℃; for 18h; Inert atmosphere;
DOI:10.1021/ja2108992

Reference yield:

: 2142-68-9
1-(2-chlorophenyl)ethanone

: 1359978-77-0
(E)-N'-(1-(2-((Z)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(methylthio)vinyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide

Guidance literature:: Multi-step reaction with 3 steps

1: N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

2: [Rh(κ2P,P-DPEphos)(ν6-o-xylene)][BArF4] / o-xylene / 4 h / 60 °C / Inert atmosphere

3: acetic acid / ethanol / 18 h / 20 °C / Inert atmosphere

With [Rh(κ2P,P-DPEphos)(ν6-o-xylene)][BArF4]; acetic acid; In ethanol; o-xylene; N,N-dimethyl-formamide;
DOI:10.1021/ja2108992

Reference yield:

: 1441-97-0
2'-(methylthio)acetophenone

: 88444-81-9
3,5-bis(trifluoromethyl)phenylacetylene

: 1359978-77-0
(E)-N'-(1-(2-((Z)-2-(3,5-bis(trifluoromethyl)phenyl)-2-(methylthio)vinyl)phenyl)ethylidene)-4-methylbenzenesulfonohydrazide

Guidance literature:: Multi-step reaction with 2 steps

1: [Rh(κ2P,P-DPEphos)(ν6-o-xylene)][BArF4] / o-xylene / 4 h / 60 °C / Inert atmosphere

2: acetic acid / ethanol / 18 h / 20 °C / Inert atmosphere

With [Rh(κ2P,P-DPEphos)(ν6-o-xylene)][BArF4]; acetic acid; In ethanol; o-xylene;
DOI:10.1021/ja2108992