2-methyl-7-phenyl-1H-indene

Base Information

Chemical Name:2-methyl-7-phenyl-1H-indene
CAS No.:153733-75-6
Molecular Formula:C16H14
Molecular Weight:206.287
Hs Code.:2902909090
European Community (EC) Number:640-068-4
DSSTox Substance ID:DTXSID30401627
Wikidata:Q72494888
Mol file:153733-75-6.mol

Synonyms:2-methyl-7-phenyl-1H-indene;153733-75-6;2-Methyl-7-phenylindene;2-METHYL-7-PHENYL-1H-INDENE, 97;MFCD00674042;DTXSID30401627;JQCCMEDYANGBOG-UHFFFAOYSA-N;AKOS015966754;AM84493;AS-60642;BB 0220668;CS-0328654;D86777;A854839

Suppliers and Price of 2-methyl-7-phenyl-1H-indene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-Methyl-7-phenylindene
5g
$ 250.00

Crysdot
2-Methyl-7-phenyl-1H-indene 95+%
1g
$ 510.00

Arctom
2-Methyl-7-phenyl-1H-indene 98%
1g
$ 318.00

American Custom Chemicals Corporation
2-METHYL-7-PHENYL-1H-INDENE 95.00%
5MG
$ 497.11

Alichem
2-Methyl-7-phenyl-1H-indene
1g
$ 457.60

Alichem
2-Methyl-7-phenyl-1H-indene
250mg
$ 201.88

Total 29 raw suppliers

Chemical Property of 2-methyl-7-phenyl-1H-indene

Chemical Property:

Melting Point:47-49 °C(lit.)
Refractive Index:1.5000 (estimate)
Boiling Point:358.985 °C at 760 mmHg
Flash Point:183.712 °C
PSA：0.00000
Density:1.057 g/cm³
LogP:4.31300
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
XLogP3:4.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:1
Exact Mass:206.109550447
Heavy Atom Count:16
Complexity:270

Purity/Quality:

97% ^*data from raw suppliers

2-Methyl-7-phenylindene ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36/37/39-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC2=C(C1)C(=CC=C2)C3=CC=CC=C3
Uses 2-Methyl-7-phenylindene is used for the preparation of metallocene complexes with heteroatom containing n-ligands as a catalyst for olefin polymerization.

Technology Process of 2-methyl-7-phenyl-1H-indene

There total 7 articles about 2-methyl-7-phenyl-1H-indene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 29.0%

: 153733-74-5
2-methyl-4-phenyl-1H-indan-1-one

: 153733-75-6
2-methyl-7-phenyl-1H-indene

Guidance literature:: With sodium tetrahydroborate; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; toluene; at 0 - 20 ℃; for 2h; Reflux;

Reference yield:

: 468756-77-6
4⁽⁷⁾-chloro-2-methyl-1⁽³⁾H-indene

: 100-58-3
phenylmagnesium bromide

: 153733-75-6
2-methyl-7-phenyl-1H-indene

Guidance literature:

Reference yield:

: 108-86-1,52753-63-6
bromobenzene

: 153733-75-6
2-methyl-7-phenyl-1H-indene

Guidance literature:: Multi-step reaction with 5 steps

1.1: magnesium / tetrahydrofuran / 3 h / Reflux

1.2: 50 - 55 °C

2.1: N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) / tetrachloromethane / 5 h / 90 °C

3.1: sodium / ethanol / 3 h / 130 °C

3.2: 4 h / 100 °C

4.1: thionyl chloride / 18 h / 20 °C

4.2: 1 h / 80 °C

5.1: sodium tetrahydroborate; toluene-4-sulfonic acid / tetrahydrofuran; toluene; methanol / 2 h / 0 - 20 °C / Reflux

With sodium tetrahydroborate; N-Bromosuccinimide; thionyl chloride; 2,2'-azobis(isobutyronitrile); sodium; toluene-4-sulfonic acid; magnesium; In tetrahydrofuran; methanol; tetrachloromethane; ethanol; toluene;