6-methylidenetridecane

Base Information

• Chemical Name: 6-methylidenetridecane
• CAS No.: 53056-37-4
• Molecular Formula: C₁₄H₂₈
• Molecular Weight: 196.376
• Mol file: 53056-37-4.mol

Synonyms:2-pentyl-non-1-ene

Chemical Property of 6-methylidenetridecane

Chemical Property:

• Vapor Pressure: 0.037mmHg at 25°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-methylidenetridecane

There total 9 articles about 6-methylidenetridecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 2.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1-Heptene (592-76-7) → 2-pentyl-non-1-ene (53056-37-4) + C14H28 + 2,4-diphenylbut-1-ene (16606-47-6) + non-1-en-2-ylbenzene (24066-87-3) + C15H22 (1613456-13-5) + C15H22 (1613456-11-3) + C17H26

Guidance literature:

In n-heptane; at 100 ℃; for 18h; Reagent/catalyst; Temperature; Concentration; Catalytic behavior; Sealed tube;

DOI:10.1021/om500231t

Reference yield:

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + n-heptane (142-82-5) → 2-pentyl-non-1-ene (53056-37-4) + ethylbenzene (100-41-4,27536-89-6) + C14H28 + 2,4-diphenylbut-1-ene (16606-47-6) + 2-(phenethyl)hept-1-ene (1613456-12-4)

Guidance literature:

With [(1,3-bis((di-tert-butylphosphino)methyl)benzene(-1H))IrH₂]; Cp*TaCl₂(C₂H₄); at 100 ℃; for 72h; Time; Temperature; Concentration; Catalytic behavior; Inert atmosphere; Schlenk technique;

Reference yield:

1-hexene (592-41-6,25067-06-5) + n-heptane (142-82-5) → 2-butyl-1-octene (5698-48-6) + hexane (110-54-3) + 2-pentyl-non-1-ene (53056-37-4) + C14H28 + 5-methylenedodecane (54248-54-3) + C13H26 (1463474-94-3) + C13H26 (1463474-96-5) + C13H26 (55111-03-0) + 6-methyl-5-methylenedecane + 2-hexene (592-43-8)

Guidance literature:

With [(1,3-bis((di-tert-butylphosphino)methyl)benzene(-1H))IrH₂]; Cp*TaCl₂(C₂H₄); at 100 ℃; for 5h; Temperature; Concentration; Catalytic behavior; Inert atmosphere; Schlenk technique;

upstream raw materials:

1-hexene

tert-butylethylene

n-heptane

styrene

Downstream raw materials:

6-tridecanone

Refernces

• 1、 -. "TANDEM TRANSFER HYDROGENATION AND OLIGOMERIZATION FOR HYDROCARBON PRODUCTION". Paragraph 0112-0114. . Retrieved 2014/07/23.
• 2、 Leitch, David C.,Lam, Yan Choi,Labinger, Jay A.,Bercaw, John E.. "Upgrading light hydrocarbons via tandem catalysis: A dual homogeneous Ta/Ir system for alkane/alkene coupling". supporting information. p. 10302 - 10305. Retrieved 2013/08/23.