N'-acryloyl-4-methyl-N-(2-methylallyl)benzenesulfonohydrazide

Base Information

• Chemical Name: N'-acryloyl-4-methyl-N-(2-methylallyl)benzenesulfonohydrazide
• CAS No.: 1173165-21-3
• Molecular Formula: C₁₄H₁₈N₂O₃S
• Molecular Weight: 294.375
• Mol file: 1173165-21-3.mol

Synonyms:N'-acryloyl-4-methyl-N-(2-methylallyl)benzenesulfonohydrazide

Chemical Property of N'-acryloyl-4-methyl-N-(2-methylallyl)benzenesulfonohydrazide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of N'-acryloyl-4-methyl-N-(2-methylallyl)benzenesulfonohydrazide

There total 1 articles about N'-acryloyl-4-methyl-N-(2-methylallyl)benzenesulfonohydrazide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

4-methyl-N-(2-methylallyl)benzenesulfonohydrazide (1173165-17-7) + acryloyl chloride (814-68-6,25189-84-8) → N'-acryloyl-4-methyl-N-(2-methylallyl)benzenesulfonohydrazide (1173165-21-3)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1016/j.tet.2009.07.076

Reference yield: 70.0%

N'-acryloyl-4-methyl-N-(2-methylallyl)benzenesulfonohydrazide (1173165-21-3) → 5-methylpyridazin-3(2H)-one (54709-94-3)

Guidance literature:

With 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(iso-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methylene ruthenium(II) dichloride; In dichloromethane; at 70 ℃; for 72h; Sealed tube; Inert atmosphere;

DOI:10.1039/b904363b

Reference yield:

N'-acryloyl-4-methyl-N-(2-methylallyl)benzenesulfonohydrazide (1173165-21-3) → C12H14N2O3S

Guidance literature:

With 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene[2-(iso-propoxy)-5-(N,N-dimethylaminosulfonyl)phenyl]methylene ruthenium(II) dichloride; In dichloromethane; at 70 ℃;

DOI:10.1016/j.tet.2009.07.076

upstream raw materials:

4-methyl-N-(2-methylallyl)benzenesulfonohydrazide

acryloyl chloride

Downstream raw materials:

5-methylpyridazin-3(2H)-one