[RuH(1,2-bis(dicyclohexylphosphino)ethane)2][PF₆]

Base Information

Chemical Name:[RuH(1,2-bis(dicyclohexylphosphino)ethane)2][PF₆]
CAS No.:121832-84-6
Molecular Formula:C₅₂H₉₇P₄Ru*F₆P
Molecular Weight:1092.27
Hs Code.:

[RuH(1,2-bis(dicyclohexylphosphino)ethane)2][PF<sub>6</sub>]

Synonyms:[RuH(1,2-bis(dicyclohexylphosphino)ethane)2][PF₆]

Suppliers and Price of [RuH(1,2-bis(dicyclohexylphosphino)ethane)2][PF₆]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [RuH(1,2-bis(dicyclohexylphosphino)ethane)2][PF₆]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [RuH(1,2-bis(dicyclohexylphosphino)ethane)2][PF₆]

There total 7 articles about [RuH(1,2-bis(dicyclohexylphosphino)ethane)2][PF₆] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: ammonium hexafluorophosphate

: dichlorotetrakis(dimethylsulfoxide)ruthenium(II)

: 64-17-5
ethanol

: 23743-26-2
1,2-bis-(dicyclohexylphosphino)ethane

: 121832-84-6
[RuH(1,2-bis(dicyclohexylphosphino)ethane)2][PF₆]

Guidance literature:: With HN(i)Pr₂; In ethanol; Ar-atmosphere; refluxing Ru-complex with 2 equiv. diphosphine and excessi-Pr2NH for 3 h, pptn. on NH4PF6 addn.; stirring for 30 min, decantation, washing (hot EtOH), extn. into CH2Cl2,evapn., recrystn. (CH2Cl2, slow concn.); elem. anal.;
DOI:10.1021/ic970583m

Reference yield: 63.0%

: 60969-19-9
thallium(I) hexafluorophosphate

: 121832-67-5
trans-{RuH(Cl)(1,2-bis(dicyclohexylphosphino)ethane)2}

: 121832-84-6
[RuH(1,2-bis(dicyclohexylphosphino)ethane)2][PF₆]

Guidance literature:: In methanol; (inert atm.); pptn. (2 h); cooling (ice), decanting, drying (vac.), recrystn. (CH2Cl2-iPrOH); elem.anal.;
DOI:10.1039/a808860h

Reference yield: 39.0%

: ammonium hexafluorophosphate

: trans-[RuCl(CH=CH2)(κ(2)-1,2-C2H4(PCy2)2)2]

: 121832-84-6
[RuH(κ(2)-1,2-C2H4(PCy2)2)2]PF6

: trans-[RuCl(=CHCH3)(κ(2)-1,2-C2H4(PCy2)2)2]PF6

Guidance literature:: With HBF₄; In diethyl ether; dichloromethane; all operations under Ar; soln. of Ru compd. in CH2Cl2 treated with soln.of B compd. in ether, stirred for 30 min at -78°C, solvent evapd . in vac., washed with ether, suspd. in MeOH, treated with MeOH soln. ofP compd., stirred for 25 min at room; ppt. sepd., solid washed with MeOH, dried, from mother liquor H complex sepd., elem. anal.;
DOI:10.1002/1099-0682(200108)2001:8<1957::AID-EJIC1957>3.0.CO;2-E