1,6-dibismuthatriptycene

Base Information

• Chemical Name: 1,6-dibismuthatriptycene
• CAS No.: 99516-61-7
• Molecular Formula: C₁₈H₁₂Bi₂
• Molecular Weight: 646.254
• Mol file: 99516-61-7.mol

Synonyms:1,6-dibismuthatriptycene

Chemical Property of 1,6-dibismuthatriptycene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,6-dibismuthatriptycene

There total 1 articles about 1,6-dibismuthatriptycene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bismuth (7440-69-9) + o-phenylenemercury, cyclic trimer (20742-67-0) → triphenylene (217-59-4) + 1,6-dibismuthatriptycene (99516-61-7)

Guidance literature:

In neat (no solvent); byproducts: mercury, hexaphenylene; finely powdered Bi intimately mixed with (HgC6H4)3 was heated in a sealed tube at 250°C for 2 h; extd. with petroleum ether, ext. was subjected to preparative TLC on SiO2 (petroleum ether-Et2O); products were identified by mass spectrometry;

DOI:10.1016/0022-328X(87)80347-9

Reference yield:

1,6-dibismuthatriptycene (99516-61-7) → triphenylene (217-59-4)

Guidance literature:

In neat (no solvent); byproducts: hexaphenylene; slow decompn. at 250°C; sepd. by preparative TLC (SiO2, petroleum ether-Et2O as eluent);

DOI:10.1016/0022-328X(87)80347-9

upstream raw materials:

bismuth

o-phenylenemercury, cyclic trimer

Downstream raw materials:

triphenylene

Refernces