C,N-diphenylnitrone

Base Information

• Chemical Name: C,N-diphenylnitrone
• CAS No.: 201024-81-9
• Molecular Formula: C₁₃H₁₁NO
• Molecular Weight: 197.236
• Mol file: 201024-81-9.mol

Synonyms:C,N-diphenylnitrone

Chemical Property of C,N-diphenylnitrone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C,N-diphenylnitrone

There total 76 articles about C,N-diphenylnitrone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

N-benzyl-N-phenylhydroxylamine (3376-40-7) → N-(benzylidene)aniline N-oxide (1137-96-8,26505-49-7,201024-81-9)

Guidance literature:

With rhodium nanoparticles supported on carbon nanotube; In methanol; at 20 ℃; for 2h;

DOI:10.1002/cctc.201601155

Reference yield: 98.0%

benzaldehyde (100-52-7) + N-Phenylhydroxylamine (100-65-2) → N-(benzylidene)aniline N-oxide (1137-96-8,26505-49-7,201024-81-9)

Guidance literature:

In glycerol; at 60 - 80 ℃; for 0.25h; Green chemistry;

DOI:10.1007/s12039-019-1677-7

Reference yield: 94.0%

benzaldehyde (100-52-7) + aniline (62-53-3) → N-(benzylidene)aniline N-oxide (1137-96-8,26505-49-7,201024-81-9)

Guidance literature:

With Oxone; In acetonitrile; at 5 - 20 ℃; for 4.5h; Reagent/catalyst; Solvent; Green chemistry;

DOI:10.1016/j.tetlet.2014.08.049

upstream raw materials:

phenyldiazomethane

Nitrosobenzene

benzene

N-benzyl-N-phenylhydroxylamine

Downstream raw materials:

E-[2-methoxy-1-phenyl-methylene]-phenylamine

2-phenyl-2-(phenylimino)acetonitrile

3-(((2-cyanopropan-2-yl)oxy)(phenyl)amino)-2,2-dimethyl-3-phenylpropanenitrile

N-diphenylmethylene-N-pheylnitrone

Refernces

• 1、 Hollis, W. Gary,Smith, Philip L.,Hood, David K.,Cook, Stacie M.. "Reaction of Trialkylboranes with Nitrones: A Novel Route to α-Alkylated Hydroxylamines". . p. 3485 - 3486. Retrieved 1994.
• 2、 Angert, Janet L.,Hurst, Alan F.,Lowry, Susan A.,Landolt, Robert G.. "Interaction of Phenylhydrazones with Nitrosobenzene-Radical Intermediates". . p. 168 - 170. Retrieved 1981.
• 3、 Neimann et al.. "-". . p. 3157. Retrieved 1965.
• 4、 Liang, Dong-Dong,Guo, Shen-Yi,Tong, Shuo,Wang, Mei-Xiang. "Polyfunctionalized biaryls accessed by a one-pot nucleophilic aromatic substitution and sigmatropic rearrangement reaction cascade under mild conditions". supporting information. . Retrieved 2021/02/09.
• 5、 -. "Method for converting terminal alkyne into amide and application of method in construction of gene coding library". Paragraph 0057-0059. . Retrieved 2021/12/07.