methyl (1R,2R)-1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-indene-2-carboxylate

Base Information

Chemical Name:methyl (1R,2R)-1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-indene-2-carboxylate
CAS No.:1196785-50-8
Molecular Formula:C₁₉H₁₈O₃
Molecular Weight:294.35
Hs Code.:

Synonyms:methyl (1R,2R)-1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-indene-2-carboxylate

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Chemical Property of methyl (1R,2R)-1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-indene-2-carboxylate

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Technology Process of methyl (1R,2R)-1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-indene-2-carboxylate

There total 4 articles about methyl (1R,2R)-1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-indene-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 869997-77-3
(E)-3-(2-((E)-3-oxo-3-phenylprop-1-enyl)phenyl)acrylaldehyde

: 67-56-1
methanol

: 1196785-50-8
methyl (1R,2R)-1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-indene-2-carboxylate

Guidance literature:: (E)-3-(2-((E)-3-oxo-3-phenylprop-1-enyl)phenyl)acrylaldehyde; With BF₄^(1-)*C₂₂H₃₀N₃O⁽¹⁺⁾; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 - 45 ℃; Inert atmosphere;

methanol; In dichloromethane; at 20 ℃; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1039/b914805a

Reference yield: 98.0%

: 67-56-1
methanol

: (4aR, 9aR)-3-phenyl-9,9a-dihydroindeno[2,1-c]pyran-1(4aH)-one

: 1196785-50-8
methyl (1R,2R)-1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-indene-2-carboxylate

Guidance literature:: at 20 - 25 ℃; for 16h; stereospecific reaction;
DOI:10.1021/ja109975c

Reference yield:

: 869997-77-3
(E)-3-(2-((E)-3-oxo-3-phenylprop-1-enyl)phenyl)acrylaldehyde

: 67-56-1
methanol

: (1S,2S)-methyl 1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-indene-2-carboxylate

: 1196785-50-8
methyl (1R,2R)-1-(2-oxo-2-phenylethyl)-2,3-dihydro-1H-indene-2-carboxylate

Guidance literature:: (E)-3-(2-((E)-3-oxo-3-phenylprop-1-enyl)phenyl)acrylaldehyde; With (5aS,6R,9S,9aR)-6,11,11-trimethyl-2-phenyl-5a,6,7,8,9,9a-hexahydro-4H-6,9-methano-benzo[b][1,2,4]triazolo[4,3-d][1,4]oxazin-2-ium tetrafluoroborate; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 - 45 ℃; Inert atmosphere;

methanol; In dichloromethane; at 20 ℃; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1039/b914805a