S-ethyl (1R,3S)-3-{[tert-butyl(diphenyl)silyl]oxy}cyclohexane carbothiolate

Base Information

Chemical Name:S-ethyl (1R,3S)-3-{[tert-butyl(diphenyl)silyl]oxy}cyclohexane carbothiolate
CAS No.:521274-58-8
Molecular Formula:C₂₅H₃₄O₂SSi
Molecular Weight:426.695
Hs Code.:

Synonyms:S-ethyl (1R,3S)-3-{[tert-butyl(diphenyl)silyl]oxy}cyclohexane carbothiolate

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Chemical Property of S-ethyl (1R,3S)-3-{[tert-butyl(diphenyl)silyl]oxy}cyclohexane carbothiolate

Chemical Property:

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Technology Process of S-ethyl (1R,3S)-3-{[tert-butyl(diphenyl)silyl]oxy}cyclohexane carbothiolate

There total 3 articles about S-ethyl (1R,3S)-3-{[tert-butyl(diphenyl)silyl]oxy}cyclohexane carbothiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-08-1
ethanethiol

: 875928-18-0
(1R,3S)-3-(tert-butyldiphenylsilanyloxy)cyclohexane-1-carboxylic acid

: 521274-58-8
S-ethyl (1R,3S)-3-{[tert-butyl(diphenyl)silyl]oxy}cyclohexane carbothiolate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In toluene; at 20 ℃; for 1h;
DOI:10.1021/ja0340679

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 521274-58-8
S-ethyl (1R,3S)-3-{[tert-butyl(diphenyl)silyl]oxy}cyclohexane carbothiolate

Guidance literature:: Multi-step reaction with 2 steps

1.1: imidazole / dimethylformamide / 1 h / 20 °C

1.2: H₂ / 10 percent Pd/C / ethyl acetate / 12 h / 760 Torr

2.1: DCC; DMAP / toluene / 1 h / 20 °C

With 1H-imidazole; dmap; dicyclohexyl-carbodiimide; In N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja0340679

Reference yield:

: 521274-50-0
benzyl (1R,5R)-5-hydroxycyclohex-3-ene-1-carboxylate

: 521274-58-8
S-ethyl (1R,3S)-3-{[tert-butyl(diphenyl)silyl]oxy}cyclohexane carbothiolate

Guidance literature:: Multi-step reaction with 2 steps

1.1: imidazole / dimethylformamide / 1 h / 20 °C

1.2: H₂ / 10 percent Pd/C / ethyl acetate / 12 h / 760 Torr

2.1: DCC; DMAP / toluene / 1 h / 20 °C

With 1H-imidazole; dmap; dicyclohexyl-carbodiimide; In N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja0340679