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1-Bromo-3-(methoxymethoxy)-2-methylbenzene

Base Information Edit
  • Chemical Name:1-Bromo-3-(methoxymethoxy)-2-methylbenzene
  • CAS No.:149981-99-7
  • Molecular Formula:C9H11BrO2
  • Molecular Weight:231.089
  • Hs Code.:
  • Mol file:149981-99-7.mol
1-Bromo-3-(methoxymethoxy)-2-methylbenzene

Synonyms:1-Bromo-3-(methoxymethoxy)-2-methylbenzene

Suppliers and Price of 1-Bromo-3-(methoxymethoxy)-2-methylbenzene
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
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Total 1 raw suppliers
Chemical Property of 1-Bromo-3-(methoxymethoxy)-2-methylbenzene Edit
Chemical Property:
Purity/Quality:

99% *data from raw suppliers

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Technology Process of 1-Bromo-3-(methoxymethoxy)-2-methylbenzene

There total 1 articles about 1-Bromo-3-(methoxymethoxy)-2-methylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
3-bromo-2-methylphenol; With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 1h;
chloromethyl methyl ether; In DMF (N,N-dimethyl-formamide); at 20 ℃; for 1h;
Guidance literature:
1-Bromo-3-(methoxymethoxy)-2-methylbenzene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h;
With Triisopropyl borate; In tetrahydrofuran; at -78 ℃; for 0.75h;
With hydrogenchloride; In tetrahydrofuran; water;
Guidance literature:
Multi-step reaction with 6 steps
1: 1.) PhLi, 2.) CuBr / 1.) Et2O, reflux, 7 h, 2.) EtO2, r.t., overnight
2: 1.) tetramethylethylenediamine, BuLi / 1.) Et2O, hexane, 0 deg C, 1 h, 2.) -25 deg C, 5 min
3: 57 percent / diethyl ether
4: 93 percent / LiAlH4 / diethyl ether / 1 h / 0 °C
5: 64 percent / LiAlH4, titanocene dichloride / tetrahydrofuran / 2.5 h / Heating
6: 63 percent / salcomine, O2 / ethanol / 1 h / 10 °C / 912 - 1064 Torr
With lithium aluminium tetrahydride; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; salcomine; titanocene dichloride; oxygen; phenyllithium; copper(I) bromide; In tetrahydrofuran; diethyl ether; ethanol;
DOI:10.1002/hlca.19930760429
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