5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-1,4-di-O-methanesulfonyl-L-lyxitol

Base Information

Chemical Name:5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-1,4-di-O-methanesulfonyl-L-lyxitol
CAS No.:1006032-29-6
Molecular Formula:C₂₆H₃₈O₉S₂Si
Molecular Weight:586.8
Hs Code.:

Synonyms:5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-1,4-di-O-methanesulfonyl-L-lyxitol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-1,4-di-O-methanesulfonyl-L-lyxitol

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Technology Process of 5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-1,4-di-O-methanesulfonyl-L-lyxitol

There total 7 articles about 5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-1,4-di-O-methanesulfonyl-L-lyxitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 1006364-60-8
5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-L-lyxitol

: 124-63-0
methanesulfonyl chloride

: 1006032-29-6
5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-1,4-di-O-methanesulfonyl-L-lyxitol

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1021/ol7025558

Reference yield:

: 152006-17-2
2,3-O-isopropylidene-L-lyxono-1,4-lactone

: 1006032-29-6
5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-1,4-di-O-methanesulfonyl-L-lyxitol

Guidance literature:: Multi-step reaction with 2 steps

1.1: 1H-imidazole / dichloromethane / 14 h / 0 - 20 °C / Inert atmosphere

2.1: sodium tetrahydroborate / tetrahydrofuran; methanol / 1 h / 20 °C / Inert atmosphere

2.2: 20 h / 0 °C / Inert atmosphere

With 1H-imidazole; sodium tetrahydroborate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ml2001054

Reference yield:

: 1320269-76-8
(3aR,6S,6aR)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethyldihydrofuro[3,4-d][1,3]dioxol-4(3aH)-one

: 124-63-0
methanesulfonyl chloride

: 1006032-29-6
5-O-tert-butyldiphenylsilyl-2,3-O-isopropylidene-1,4-di-O-methanesulfonyl-L-lyxitol

Guidance literature:: C₂₄H₃₀O₅Si; With sodium tetrahydroborate; In tetrahydrofuran; methanol; at 20 ℃; for 1h; Inert atmosphere;

methanesulfonyl chloride; With pyridine; In dichloromethane; at 0 ℃; for 20h; Inert atmosphere;
DOI:10.1021/ml2001054