N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide

Base Information

Chemical Name:N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide
CAS No.:153681-98-2
Molecular Formula:C₂₂H₃₁NO₂SSi
Molecular Weight:401.645
Hs Code.:

Synonyms:N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide

Suppliers and Price of N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide

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Technology Process of N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide

There total 1 articles about N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 100-39-0
benzyl bromide

: 119461-42-6
(S)-N-(p-toluenesulfonyl)-4-amino-1-Z-(trimethylsilyl)-1-pentene

: 153681-98-2
N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 25 ℃; for 12h;
DOI:10.1021/jo971706n

Reference yield: 80.0%

: 153681-98-2
N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide

: 153681-99-3
(S)-N-benzyl-N-(Z)-(1-methyl-4-trimethylsilylbut-3-enyl)amine

Guidance literature:: With disodium hydrogenphosphate; sodium amalgam; In methanol; for 12h; Heating;
DOI:10.1021/jo971706n

Reference yield:

: 153681-98-2
N-Benzyl-4-methyl-N-((Z)-(S)-1-methyl-4-trimethylsilanyl-but-3-enyl)-benzenesulfonamide

: 88034-71-3
(+)-(S)-2-methylpiperidinyl-(R)-2-methoxy-2-phenyl-3,3,3-trifluoropropanamide

Guidance literature:: Multi-step reaction with 5 steps

1: 80 percent / Na/Hg, Na₂HPO₄ / methanol / 12 h / Heating

2: 53 percent / K₂CO₃ / acetonitrile / 48 h / Heating

3: 61 percent / (n-Bu₄N)2Ce(NO₃)6 / acetonitrile / 18 h / 25 °C

4: 28 percent / HCOONH₄ / Pd/C / methanol / 0.17 h / Heating

5: 4 mg / 4-DMAP, pyridine / acetonitrile / 12 h / Heating

With pyridine; dmap; disodium hydrogenphosphate; sodium amalgam; tetrabutylammonium hexanitratocerate(IV); ammonium formate; potassium carbonate; palladium on activated charcoal; In methanol; acetonitrile;
DOI:10.1021/jo971706n