(2S,3S,4R,5S,6S)-1-<(tert-butyldiphenylsilyl)oxy>-3-<(triethylsilyl)oxy>-2,4,6-trimethyloct-7-ene

Base Information

Chemical Name:(2S,3S,4R,5S,6S)-1-<(tert-butyldiphenylsilyl)oxy>-3-<(triethylsilyl)oxy>-2,4,6-trimethyloct-7-ene
CAS No.:129032-49-1
Molecular Formula:C₃₃H₅₄O₃Si₂
Molecular Weight:554.961
Hs Code.:

Synonyms:(2S,3S,4R,5S,6S)-1-<(tert-butyldiphenylsilyl)oxy>-3-<(triethylsilyl)oxy>-2,4,6-trimethyloct-7-ene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3S,4R,5S,6S)-1-<(tert-butyldiphenylsilyl)oxy>-3-<(triethylsilyl)oxy>-2,4,6-trimethyloct-7-ene

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Technology Process of (2S,3S,4R,5S,6S)-1-<(tert-butyldiphenylsilyl)oxy>-3-<(triethylsilyl)oxy>-2,4,6-trimethyloct-7-ene

There total 19 articles about (2S,3S,4R,5S,6S)-1-<(tert-butyldiphenylsilyl)oxy>-3-<(triethylsilyl)oxy>-2,4,6-trimethyloct-7-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 92817-88-4
(2S)-3-{[tert-butyl(diphenyl)silyl]oxy}-2-methylpropanal

: 129032-49-1
(2S,3S,4R,5S,6S)-1-<(tert-butyldiphenylsilyl)oxy>-3-<(triethylsilyl)oxy>-2,4,6-trimethyloct-7-ene

Guidance literature:: Multi-step reaction with 4 steps

1: 75 percent / 4A mol sieves / toluene / -78 °C

2: Et₃N / dimethylformamide

3: 1) ozone, 2)Me₂S / 1) MeOH, -78 deg C, 2) MeOH, -78 deg C to RT

4: 4A mol. sieves / toluene / -78 °C

With dimethylsulfide; 4 A molecular sieve; ozone; triethylamine; In N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja00237a082

Reference yield:

: 99687-40-8,106357-20-4,106357-33-9,99745-86-5
(R,R)-[(E)-2-butenyl]diisopropyl tartrate boronate

: 106568-13-2
(2S,3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-2,4-dimethyl-3-triethylsilanyloxy-pentanal

: 129032-49-1
(2S,3S,4R,5S,6S)-1-<(tert-butyldiphenylsilyl)oxy>-3-<(triethylsilyl)oxy>-2,4,6-trimethyloct-7-ene

Guidance literature:: With 4 A molecular sieve; In toluene; at -78 ℃; Yield given;
DOI:10.1021/ja00237a082

Reference yield:

: 99687-40-8,106357-20-4,106357-33-9,99745-86-5
(R,R)-[(E)-2-butenyl]diisopropyl tartrate boronate

: 106568-13-2
(2S,3S,4S)-5-(tert-Butyl-diphenyl-silanyloxy)-2,4-dimethyl-3-triethylsilanyloxy-pentanal

: 129170-53-2
(3S,4R,5R,6S,7S)-8-(tert-Butyl-diphenyl-silanyloxy)-3,5,7-trimethyl-6-triethylsilanyloxy-oct-1-en-4-ol

: 129032-49-1
(2S,3S,4R,5S,6S)-1-<(tert-butyldiphenylsilyl)oxy>-3-<(triethylsilyl)oxy>-2,4,6-trimethyloct-7-ene

Guidance literature:: With 4 A molecular sieve; In toluene; at -78 ℃; for 11h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;