(2R,4R)-1-(4-methoxybenzyloxy)-2,4-bis(tert-butyldimethylsilyloxy)hept-6-ene

Base Information

Chemical Name:(2R,4R)-1-(4-methoxybenzyloxy)-2,4-bis(tert-butyldimethylsilyloxy)hept-6-ene
CAS No.:1000694-64-3
Molecular Formula:C₂₇H₅₀O₄Si₂
Molecular Weight:494.863
Hs Code.:

Synonyms:(2R,4R)-1-(4-methoxybenzyloxy)-2,4-bis(tert-butyldimethylsilyloxy)hept-6-ene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,4R)-1-(4-methoxybenzyloxy)-2,4-bis(tert-butyldimethylsilyloxy)hept-6-ene

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Technology Process of (2R,4R)-1-(4-methoxybenzyloxy)-2,4-bis(tert-butyldimethylsilyloxy)hept-6-ene

There total 6 articles about (2R,4R)-1-(4-methoxybenzyloxy)-2,4-bis(tert-butyldimethylsilyloxy)hept-6-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: C₂₁H₃₆O₄Si

: tert-butyldimethylsilyl trifluoromethanesulfonate

: 1000694-64-3
(2R,4R)-1-(4-methoxybenzyloxy)-2,4-bis(tert-butyldimethylsilyloxy)hept-6-ene

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at -78 ℃; for 1h;
DOI:10.1002/anie.201407806

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: (2R,4R)-1-[(4-methoxybenzyl)oxy]-6-heptene-2,4-diol

: 1000694-64-3
(2R,4R)-1-(4-methoxybenzyloxy)-2,4-bis(tert-butyldimethylsilyloxy)hept-6-ene

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃;
DOI:10.1021/ja076580i

Reference yield:

: 1449419-18-4
(R)-1-(1′,3′-dithian-2-yl)-3-(4′′-methoxybenzyloxy)propan-2-ol

: 1000694-64-3
(2R,4R)-1-(4-methoxybenzyloxy)-2,4-bis(tert-butyldimethylsilyloxy)hept-6-ene

Guidance literature:: Multi-step reaction with 4 steps

1: 2,6-dimethylpyridine / dichloromethane / 5 h / -78 °C

2: methyl iodide; calcium carbonate / acetonitrile; water / 6 h / 20 °C / Reflux

3: tetrahydrofuran / 2 h / -78 °C

4: 2,6-dimethylpyridine / dichloromethane / 1 h / -78 °C

With 2,6-dimethylpyridine; calcium carbonate; methyl iodide; In tetrahydrofuran; dichloromethane; water; acetonitrile;
DOI:10.1002/anie.201407806