3,4-Pyrrolidinediol, 2-ethenyl-1-(phenylmethyl)-, (2R,3S,4S)- (9CI)

Base Information

Chemical Name:3,4-Pyrrolidinediol, 2-ethenyl-1-(phenylmethyl)-, (2R,3S,4S)- (9CI)
CAS No.:357278-44-5
Molecular Formula:C₁₃H₁₇NO₂
Molecular Weight:219.283
Hs Code.:
Mol file:357278-44-5.mol

Synonyms:3,4-Pyrrolidinediol, 2-ethenyl-1-(phenylmethyl)-, (2R,3S,4S)- (9CI)

Suppliers and Price of 3,4-Pyrrolidinediol, 2-ethenyl-1-(phenylmethyl)-, (2R,3S,4S)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 3,4-Pyrrolidinediol, 2-ethenyl-1-(phenylmethyl)-, (2R,3S,4S)- (9CI)

Chemical Property:

PSA：0.00000
LogP:0.00000

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3,4-Pyrrolidinediol, 2-ethenyl-1-(phenylmethyl)-, (2R,3S,4S)- (9CI)

There total 11 articles about 3,4-Pyrrolidinediol, 2-ethenyl-1-(phenylmethyl)-, (2R,3S,4S)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 543690-30-8
(2R,3R,4R)-4-Benzylamino-hex-5-ene-1,2,3-triol

: 357278-44-5,608514-57-4
(2R,3R,4R)-1-Benzyl-2-vinyl-pyrrolidine-3,4-diol

Guidance literature:: With tetrachloromethane; triethylamine; triphenylphosphine; In N,N-dimethyl-formamide; at 20 ℃;
DOI:10.1002/ejoc.200300163

Reference yield: 65.0%

: 357278-42-3
(2S,3S,4R)-4-benzylamino-1,2,3-triol-hex-5-en

: 357278-44-5,608514-57-4
(2R,3S,4S)-1-Benzyl-2-vinyl-pyrrolidine-3,4-diol

Guidance literature:: With tetrachloromethane; triethylamine; triphenylphosphine; In N,N-dimethyl-formamide; at 20 ℃;
DOI:10.1055/s-2001-14593

Reference yield:

: 357278-33-2
Benzyl-{(R)-1-[(2R,3S)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-allyl}-amine

: 357278-44-5,608514-57-4
(2R,3S,4S)-1-Benzyl-2-vinyl-pyrrolidine-3,4-diol

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / TBAF on silica gel / tetrahydrofuran

2: 71 percent / Ph₃P; CCl₄; Et₃N / dimethylformamide / 20 °C

3: H₂SO₄ / H₂O; dioxane / 5 h / Heating

With tetrachloromethane; sulfuric acid; tetrabutyl ammonium fluoride; triethylamine; triphenylphosphine; In tetrahydrofuran; 1,4-dioxane; water; N,N-dimethyl-formamide; 2: Appel cyclization;
DOI:10.1002/ejoc.200300163