Benzyl-{(R)-1-[(2R,3S)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-allyl}-amine

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Chemical Name:Benzyl-{(R)-1-[(2R,3S)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-allyl}-amine
CAS No.:357278-33-2
Molecular Formula:C₂₉H₃₅NO₂Si
Molecular Weight:457.688
Hs Code.:

Synonyms:Benzyl-{(R)-1-[(2R,3S)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-allyl}-amine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzyl-{(R)-1-[(2R,3S)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-allyl}-amine

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Technology Process of Benzyl-{(R)-1-[(2R,3S)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-allyl}-amine

There total 8 articles about Benzyl-{(R)-1-[(2R,3S)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-allyl}-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 1826-67-1
vinyl magnesium bromide

: Benzyl-[1-[(2R,3S)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-meth-(E)-ylidene]-amine

: 357278-33-2
Benzyl-{(R)-1-[(2R,3S)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-allyl}-amine

Guidance literature:: With boron trifluoride diethyl etherate; In diethyl ether; at -78 ℃;
DOI:10.1016/j.tetasy.2007.06.002

Reference yield:

: 131380-35-3
(2R,3R)-4-(tert-Butyldiphenylsilyloxy)-2,3-epoxybutan-1-al

: 357278-33-2
Benzyl-{(R)-1-[(2R,3S)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-allyl}-amine

Guidance literature:: Multi-step reaction with 2 steps

1: MS 4 Angstroem / diethyl ether / 3 h / 20 °C

2: 64 percent / BF₃*Et₂O / diethyl ether / -78 °C

With MS 4 Angstroem; boron trifluoride diethyl etherate; In diethyl ether;
DOI:10.1016/j.tetasy.2007.06.002

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 357278-33-2
Benzyl-{(R)-1-[(2R,3S)-3-(tert-butyl-diphenyl-silanyloxymethyl)-oxiranyl]-allyl}-amine

Guidance literature:: Multi-step reaction with 5 steps

1: 91 percent / n-BuLi / methanol

2: 93 percent / (-)-DET; t-BuOOH; 4 Angstroem molecular sieves / Ti(O-i-Pr)4 / CH₂Cl₂ / -23 °C

3: 92 percent / IBX / dimethylsulfoxide

4: 4 Angstroem molecular sieves / diethyl ether / 20 °C

5: Et₂OBF₃ / diethyl ether / -78 °C

With tert.-butylhydroperoxide; n-butyllithium; 4 A molecular sieve; boron trifluoride diethyl etherate; (-)-diethyl tartrate; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; titanium(IV) isopropylate; In methanol; diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1039/b505303j