methyl 4-hydroxy-3-(3'-methyl-2'-butenyl)-5-(3''-methyl-2''-butenyl)benzoate

Base Information

• Chemical Name: methyl 4-hydroxy-3-(3'-methyl-2'-butenyl)-5-(3''-methyl-2''-butenyl)benzoate
• CAS No.: 98969-33-6
• Molecular Formula: C₁₈H₂₄O₃
• Molecular Weight: 288.387
• Mol file: 98969-33-6.mol

Synonyms:methyl 4-hydroxy-3-(3'-methyl-2'-butenyl)-5-(3''-methyl-2''-butenyl)benzoate

Chemical Property of methyl 4-hydroxy-3-(3'-methyl-2'-butenyl)-5-(3''-methyl-2''-butenyl)benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of methyl 4-hydroxy-3-(3'-methyl-2'-butenyl)-5-(3''-methyl-2''-butenyl)benzoate

There total 4 articles about methyl 4-hydroxy-3-(3'-methyl-2'-butenyl)-5-(3''-methyl-2''-butenyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

sodium methylparaben (5026-62-0) + prenyl bromide (870-63-3) → methyl 4-hydroxylbenzoate (99-76-3,156291-94-0) + methyl 4-hydroxy-3-(3'-methyl-2'-butenyl)-5-(3''-methyl-2''-butenyl)benzoate (98969-33-6)

Guidance literature:

at 80 ℃; for 24h;

DOI:10.1080/00397911.2017.1288823

Reference yield: 29.0%

sodium methylparaben (5026-62-0) + prenyl bromide (870-63-3) → methyl 4-((3-methylbut-2-en-1-yl)oxy)benzoate (34593-50-5) + methyl 3,5-bis(3-methylbut-2-en-1-yl)-4-((3-methylbut-2-en-1-yl)oxy)benzoate + methyl-4-methoxy-3-(3’-methyl-2’-butenyl)benzoate (101511-34-6) + methyl 4-hydroxylbenzoate (99-76-3,156291-94-0) + methyl 4-hydroxy-3-(3'-methyl-2'-butenyl)-5-(3''-methyl-2''-butenyl)benzoate (98969-33-6)

Guidance literature:

at 40 ℃; for 24h;

DOI:10.1080/00397911.2017.1288823

Reference yield:

p-Iodophenol (540-38-5) → methyl 4-hydroxy-3-(3'-methyl-2'-butenyl)-5-(3''-methyl-2''-butenyl)benzoate (98969-33-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 29 percent / NaOH

2: 89 percent / Et₃N / Cl₂Pd(PPh₃)2 / dimethylformamide / 6 h / 60 °C / 760 Torr

With sodium hydroxide; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In N,N-dimethyl-formamide;

DOI:10.1271/bbb.67.2038

upstream raw materials:

p-Iodophenol

prenyl bromide

sodium methylparaben

Downstream raw materials:

4-hydroxy-3-(3'-methyl-2'-butenyl)-5-(3''-methyl-2''-butenyl)benzoic acid