(1S,3R,5R)-3-<1(E)-(1-((triisopropylsilyl)oxy)methyl-3-tert-butoxypropenyl)>-1-<1-<2-<5-(1,3-dimethylhexahydro-2-oxo-1,3,5-triazinyl)>phenyl>ethenyl>-6-oxabicyclo<3.1.0>hexane

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Chemical Name:(1S,3R,5R)-3-<1(E)-(1-((triisopropylsilyl)oxy)methyl-3-tert-butoxypropenyl)>-1-<1-<2-<5-(1,3-dimethylhexahydro-2-oxo-1,3,5-triazinyl)>phenyl>ethenyl>-6-oxabicyclo<3.1.0>hexane
CAS No.:163980-16-3
Molecular Formula:C₃₅H₅₇N₃O₄Si
Molecular Weight:611.941
Hs Code.:

(1S,3R,5R)-3-<1(E)-(1-((triisopropylsilyl)oxy)methyl-3-tert-butoxypropenyl)>-1-<1-<2-<5-(1,3-dimethylhexahydro-2-oxo-1,3,5-triazinyl)>phenyl>ethenyl>-6-oxabicyclo<3.1.0>hexane

Synonyms:(1S,3R,5R)-3-<1(E)-(1-((triisopropylsilyl)oxy)methyl-3-tert-butoxypropenyl)>-1-<1-<2-<5-(1,3-dimethylhexahydro-2-oxo-1,3,5-triazinyl)>phenyl>ethenyl>-6-oxabicyclo<3.1.0>hexane

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Chemical Property of (1S,3R,5R)-3-<1(E)-(1-((triisopropylsilyl)oxy)methyl-3-tert-butoxypropenyl)>-1-<1-<2-<5-(1,3-dimethylhexahydro-2-oxo-1,3,5-triazinyl)>phenyl>ethenyl>-6-oxabicyclo<3.1.0>hexane

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Technology Process of (1S,3R,5R)-3-<1(E)-(1-((triisopropylsilyl)oxy)methyl-3-tert-butoxypropenyl)>-1-<1-<2-<5-(1,3-dimethylhexahydro-2-oxo-1,3,5-triazinyl)>phenyl>ethenyl>-6-oxabicyclo<3.1.0>hexane

There total 5 articles about (1S,3R,5R)-3-<1(E)-(1-((triisopropylsilyl)oxy)methyl-3-tert-butoxypropenyl)>-1-<1-<2-<5-(1,3-dimethylhexahydro-2-oxo-1,3,5-triazinyl)>phenyl>ethenyl>-6-oxabicyclo<3.1.0>hexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 152425-22-4
(1S,3R,5R)-3-<1(E)-(1-<((triisopropylsilyl)oxy)methyl>-3-tert-butoxypropenyl)>-1-<2-<5-(1,3-dimethylhexahydro-2-oxo-1,3,5-triazinyl)>benzoyl>-6-oxabicyclo<3.1.0>hexane

: 19493-09-5
Methylenetriphenylphosphorane

: 163980-16-3
(1S,3R,5R)-3-<1(E)-(1-((triisopropylsilyl)oxy)methyl-3-tert-butoxypropenyl)>-1-<1-<2-<5-(1,3-dimethylhexahydro-2-oxo-1,3,5-triazinyl)>phenyl>ethenyl>-6-oxabicyclo<3.1.0>hexane

Guidance literature:: In tetrahydrofuran; at 0 - 23 ℃;
DOI:10.1021/ja00073a057

Reference yield:

: 130749-97-2
1,3-dimethyl-5-(2-iodophenyl)-hexahydro-2-oxo-1,3,5-triazine

: 163980-16-3
(1S,3R,5R)-3-<1(E)-(1-((triisopropylsilyl)oxy)methyl-3-tert-butoxypropenyl)>-1-<1-<2-<5-(1,3-dimethylhexahydro-2-oxo-1,3,5-triazinyl)>phenyl>ethenyl>-6-oxabicyclo<3.1.0>hexane

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / 2.5percent Pd₂dba3, 22percent Ph₃As, LiCl, N-methyl-2-pyrrolidone / 70 °C / 2585.7 Torr

2: 91 percent / t-BuO₂H, triton-B / tetrahydrofuran / -15 °C

3: 92 percent / tetrahydrofuran / 0 - 23 °C

With 1-methyl-pyrrolidin-2-one; tert.-butylhydroperoxide; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; N-benzyl-trimethylammonium hydroxide; lithium chloride; In tetrahydrofuran;
DOI:10.1021/ja00073a057

Reference yield:

: 152425-13-3
(4R)-1-(trimethylstannyl)-4-<1-((triisopropylsiloxy)methyl)-3-tert-butoxy-1(E)-propenyl>cyclopentene

: 163980-16-3
(1S,3R,5R)-3-<1(E)-(1-((triisopropylsilyl)oxy)methyl-3-tert-butoxypropenyl)>-1-<1-<2-<5-(1,3-dimethylhexahydro-2-oxo-1,3,5-triazinyl)>phenyl>ethenyl>-6-oxabicyclo<3.1.0>hexane

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / 2.5percent Pd₂dba3, 22percent Ph₃As, LiCl, N-methyl-2-pyrrolidone / 70 °C / 2585.7 Torr

2: 91 percent / t-BuO₂H, triton-B / tetrahydrofuran / -15 °C

3: 92 percent / tetrahydrofuran / 0 - 23 °C

With 1-methyl-pyrrolidin-2-one; tert.-butylhydroperoxide; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; triphenyl-arsane; N-benzyl-trimethylammonium hydroxide; lithium chloride; In tetrahydrofuran;
DOI:10.1021/ja00073a057