N-(2,6-diisopropylphenyl)-9-(4-N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)perylene-3,4-dicarboximide

Base Information

• Chemical Name: N-(2,6-diisopropylphenyl)-9-(4-N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)perylene-3,4-dicarboximide
• CAS No.: 187536-92-1
• Molecular Formula: C₅₈H₄₈N₂O₄
• Molecular Weight: 837.03
• Mol file: 187536-92-1.mol

Synonyms:N-(2,6-diisopropylphenyl)-9-(4-N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)perylene-3,4-dicarboximide

Chemical Property of N-(2,6-diisopropylphenyl)-9-(4-N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)perylene-3,4-dicarboximide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(2,6-diisopropylphenyl)-9-(4-N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)perylene-3,4-dicarboximide

There total 9 articles about N-(2,6-diisopropylphenyl)-9-(4-N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)perylene-3,4-dicarboximide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.2%

N-(2,6-diisopropylphen-yl)-9-bromo-perylene-3,4-dicarboximide (165550-62-9) + 2-(2,6-diisopropylphenyl)-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-benzo[de]isoquinoline-1,3(2H)-dione → N-(2,6-diisopropylphenyl)-9-(4-N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)perylene-3,4-dicarboximide (187536-92-1)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetra(n-butyl)ammonium hydrogensulfate; potassium carbonate; In water; toluene; at 80 ℃; for 16h; Inert atmosphere;

DOI:10.1039/c6cc01187j

Reference yield: 90.0%

6-bromo-2-(2,6-diisopropylphenyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione (187536-93-2) + N-(2,6-diisopropylphenyl)-9-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-perylene-3,4-dicarboximide (695152-67-1) → N-(2,6-diisopropylphenyl)-9-(4-N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)perylene-3,4-dicarboximide (187536-92-1)

Guidance literature:

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In ethanol; toluene; at 80 ℃; for 16h;

DOI:10.1002/chem.200401177

Reference yield: 70.0%

6-bromo-2-(2,6-diisopropylphenyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione (187536-93-2) + N-(2,6-diisopropylphenyl)-9-(tributylstannyl)perylene-3,4-dicarboximide → N-(2,6-diisopropylphenyl)-9-(4-N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)perylene-3,4-dicarboximide (187536-92-1)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; for 96h; Heating;

DOI:10.1002/chem.19970030209

upstream raw materials:

6-bromo-2-(2,6-diisopropylphenyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione

N-(2,6-diisopropylphenyl)-9-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-perylene-3,4-dicarboximide

N-(2,6-diisopropylphen-yl)-9-bromo-perylene-3,4-dicarboximide

4-bromo-1,8-naphthalenedicarboxylic anhydride

Downstream raw materials:

N,N’-bis(2,6-diisopropylphenyl)-terrylene-3,4,11,12-tetracarboximide