N,N’-bis(2,6-diisopropylphenyl)-terrylene-3,4,11,12-tetracarboximide

Base Information

• Chemical Name: N,N’-bis(2,6-diisopropylphenyl)-terrylene-3,4,11,12-tetracarboximide
• CAS No.: 187536-95-4
• Molecular Formula: C₅₈H₄₆N₂O₄
• Molecular Weight: 835.014
• Mol file: 187536-95-4.mol

Synonyms:N,N’-bis(2,6-diisopropylphenyl)-terrylene-3,4,11,12-tetracarboximide

Chemical Property of N,N’-bis(2,6-diisopropylphenyl)-terrylene-3,4,11,12-tetracarboximide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N’-bis(2,6-diisopropylphenyl)-terrylene-3,4,11,12-tetracarboximide

There total 8 articles about N,N’-bis(2,6-diisopropylphenyl)-terrylene-3,4,11,12-tetracarboximide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

N-(2,6-diisopropylphenyl)-9-(4-N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)perylene-3,4-dicarboximide (187536-92-1) → N,N’-bis(2,6-diisopropylphenyl)-terrylene-3,4,11,12-tetracarboximide (187536-95-4)

Guidance literature:

With potassium carbonate; ethanolamine; at 80 ℃; for 12h;

DOI:10.1002/chem.200401177

Reference yield: 75.0%

1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)naphthalene (929103-36-6) + N-(2,6-diisopropylphenyl)-4,5-dibromonaphthalene-1,8-dicarboximide (1246857-77-1) → N,N’-bis(2,6-diisopropylphenyl)-terrylene-3,4,11,12-tetracarboximide (187536-95-4)

Guidance literature:

1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)naphthalene; N-(2,6-diisopropylphenyl)-4,5-dibromonaphthalene-1,8-dicarboximide; With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; caesium carbonate; tricyclohexylphosphine tetrafluoroborate; at 20 ℃; Schlenk technique; Inert atmosphere;

at 160 ℃; for 16h;

DOI:10.1021/acs.joc.8b00301

Reference yield: 58.0%

6-bromo-2-(2,6-diisopropylphenyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione (187536-93-2) → N,N’-bis(2,6-diisopropylphenyl)-terrylene-3,4,11,12-tetracarboximide (187536-95-4)

Guidance literature:

N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide; With potassium tert-butylate; In dekaline; (+/-)-2-methyl-1-butanol; at 160 ℃; for 0.5h;

6-bromo-2-(2,6-diisopropylphenyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione; In dekaline; (+/-)-2-methyl-1-butanol; at 100 ℃; for 1h; Product distribution / selectivity;

upstream raw materials:

N-(2,6-diisopropylphenyl)-9-(4-N-(2,6-diisopropylphenyl)naphthalene-1,8-dicarboximide)perylene-3,4-dicarboximide

N-(2,6-diisopropylphenyl)perylene-3,4-dicarboximide

6-bromo-2-(2,6-diisopropylphenyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione

1,4,5,8-naphthalenetetracarboxylic dianhydride

Downstream raw materials:

N,N’-di(2,6-diisopropylphenyl)-1,6,9,13-tetrabromoterrylene-3,4:11,12-tetracarboxdiimide