C₄₆H₅₆N₂O₇Si

Base Information

Chemical Name:C₄₆H₅₆N₂O₇Si
CAS No.:851122-06-0
Molecular Formula:C₄₆H₅₆N₂O₇Si
Molecular Weight:777.045
Hs Code.:

C<sub>46</sub>H<sub>56</sub>N<sub>2</sub>O<sub>7</sub>Si

Synonyms:C₄₆H₅₆N₂O₇Si

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Chemical Property of C₄₆H₅₆N₂O₇Si

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Technology Process of C₄₆H₅₆N₂O₇Si

There total 30 articles about C₄₆H₅₆N₂O₇Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 851121-91-0
C₄₀H₄₂N₂O₇

: 69739-34-0
t-butyldimethylsiyl triflate

: 851122-06-0
C₄₆H₅₆N₂O₇Si

Guidance literature:: With TEA; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1021/ja050203t

Reference yield:

: 351379-10-7
2-hydroxymethyl-3-iodo-6-methoxy-5-methyl-phenol

: 851122-06-0
C₄₆H₅₆N₂O₇Si

Guidance literature:: Multi-step reaction with 14 steps

1.1: 85 percent / K₂CO₃ / acetone / 4 h / Heating

2.1: sodium hydride / tetrahydrofuran; dimethylformamide / 0.17 h / 0 °C

2.2: 99 percent / TBAI / tetrahydrofuran; dimethylformamide / 12 h / 20 °C

3.1: 87 percent / TEA; TBABr; (o-tolyl)3P / Pd(OAc)2 / acetonitrile / 12 h / 80 °C

4.1: 93 percent / H₂; Rh[(COD)-(S,S)-Et-DuPhos]⁽¹⁺⁾*TfO^(1-) / CH₂Cl₂; methanol / 72 h / 20 °C / 5171.48 Torr

5.1: 93 percent / aq. LiOH / methanol; tetrahydrofuran / 11 h / 20 °C

6.1: 82 percent / sodium hydride / tetrahydrofuran / 15 h / 20 °C

7.1: BOPCl; TEA / CH₂Cl₂ / 72 h / 20 °C

8.1: DDQ; aq. buffer / CH₂Cl₂ / 0.5 h / 20 °C / pH 7.00

9.1: 84 percent / Dess-Martin periodinane; 2,6-lutidine / CH₂Cl₂ / 12 h / 20 °C

10.1: 59 percent / HCO₂H / 0.2 h / 100 °C

11.1: NaBH₄ / tetrahydrofuran; H₂O / 2 h / 20 °C

12.1: 80 percent / acetic acid; Bu₃SnH; (Ph₃P)2PdCl₂ / CH₂Cl₂ / 0.5 h / 20 °C

13.1: p-TsOH; MgSO₄ / benzene / 4 h / 85 °C

14.1: 90 percent / TEA / CH₂Cl₂ / 0.5 h / 20 °C

With 2,6-dimethylpyridine; bis-triphenylphosphine-palladium(II) chloride; lithium hydroxide; sodium tetrahydroborate; formic acid; (+)-1,2-bis((2S,,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate; TEA; tetrabutylammomium bromide; hydrogen; tri-n-butyl-tin hydride; bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; sodium hydride; magnesium sulfate; potassium carbonate; Dess-Martin periodane; toluene-4-sulfonic acid; acetic acid; tris-(o-tolyl)phosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium diacetate; In tetrahydrofuran; methanol; dichloromethane; water; N,N-dimethyl-formamide; acetone; acetonitrile; benzene; 3.1: Jeffery-Heck coupling;
DOI:10.1021/ja050203t

Reference yield:

: 351380-16-0
toluene-4-sulfonic acid 5-iodo-2-methoxy-3-methyl-phenyl ester

: 851122-06-0
C₄₆H₅₆N₂O₇Si

Guidance literature:: Multi-step reaction with 16 steps

1.1: 90 percent / aq. NaOH / ethane-1,2-diol / 5 h / Heating

2.1: Et₂AlCl / CH₂Cl₂ / 1 h / 20 °C

2.2: 86 percent / CH₂Cl₂ / 24 h / 20 °C

3.1: 85 percent / K₂CO₃ / acetone / 4 h / Heating

4.1: sodium hydride / tetrahydrofuran; dimethylformamide / 0.17 h / 0 °C

4.2: 99 percent / TBAI / tetrahydrofuran; dimethylformamide / 12 h / 20 °C

5.1: 87 percent / TEA; TBABr; (o-tolyl)3P / Pd(OAc)2 / acetonitrile / 12 h / 80 °C

6.1: 93 percent / H₂; Rh[(COD)-(S,S)-Et-DuPhos]⁽¹⁺⁾*TfO^(1-) / CH₂Cl₂; methanol / 72 h / 20 °C / 5171.48 Torr

7.1: 93 percent / aq. LiOH / methanol; tetrahydrofuran / 11 h / 20 °C

8.1: 82 percent / sodium hydride / tetrahydrofuran / 15 h / 20 °C

9.1: BOPCl; TEA / CH₂Cl₂ / 72 h / 20 °C

10.1: DDQ; aq. buffer / CH₂Cl₂ / 0.5 h / 20 °C / pH 7.00

11.1: 84 percent / Dess-Martin periodinane; 2,6-lutidine / CH₂Cl₂ / 12 h / 20 °C

12.1: 59 percent / HCO₂H / 0.2 h / 100 °C

13.1: NaBH₄ / tetrahydrofuran; H₂O / 2 h / 20 °C

14.1: 80 percent / acetic acid; Bu₃SnH; (Ph₃P)2PdCl₂ / CH₂Cl₂ / 0.5 h / 20 °C

15.1: p-TsOH; MgSO₄ / benzene / 4 h / 85 °C

16.1: 90 percent / TEA / CH₂Cl₂ / 0.5 h / 20 °C

With 2,6-dimethylpyridine; bis-triphenylphosphine-palladium(II) chloride; lithium hydroxide; sodium hydroxide; sodium tetrahydroborate; formic acid; (+)-1,2-bis((2S,,5S)-2,5-diethylphospholano)benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate; TEA; tetrabutylammomium bromide; hydrogen; tri-n-butyl-tin hydride; bis-(2-oxo-3-oxazolidinyl)phosphoryl chloride; diethylaluminium chloride; sodium hydride; magnesium sulfate; potassium carbonate; Dess-Martin periodane; toluene-4-sulfonic acid; acetic acid; tris-(o-tolyl)phosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium diacetate; In tetrahydrofuran; methanol; dichloromethane; water; ethylene glycol; N,N-dimethyl-formamide; acetone; acetonitrile; benzene; 5.1: Jeffery-Heck coupling;
DOI:10.1021/ja050203t