(phenyl isonitrile)gold(I) chloride

Base Information

Chemical Name:(phenyl isonitrile)gold(I) chloride
CAS No.:67623-10-3
Molecular Formula:C₇H₅AuClN
Molecular Weight:335.543
Hs Code.:

Synonyms:(phenyl isonitrile)gold(I) chloride

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Chemical Property of (phenyl isonitrile)gold(I) chloride

Chemical Property:

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Technology Process of (phenyl isonitrile)gold(I) chloride

There total 3 articles about (phenyl isonitrile)gold(I) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 39929-21-0
(tetrahydrothiophene)gold(I) chloride

: 1197040-29-1,931-54-4
phenyl isocyanate

: 67623-10-3
(phenyl isonitrile)gold(I) chloride

Guidance literature:: In dichloromethane; addn. of 1 equiv. of isocyanide to Au-complex soln., standing (room temp., 5 min); evapn., recrystn. (CH2Cl2/hexane); elem. anal.;
DOI:10.1016/S0020-1693(00)87441-1

Reference yield:

: 29892-37-3
chloro(dimethylsulfide) gold(I)

: 1197040-29-1,931-54-4
phenyl isocyanate

: 67623-10-3
(phenyl isonitrile)gold(I) chloride

Guidance literature:: In dichloromethane; under N2; PhNC in CH2Cl2 added dropwise to suspn. of Au complex in CH2Cl2; maintained at room temp. in the absence of light with stirring for 4 h; stored in refrigerator overnight; filtered; ppt. washed with petroleum ether;
DOI:10.1039/b617347k

Reference yield:

: 136724-23-7
μ-(1,2-diisocyanobenzene)bis(chlorogold)

: 62-53-3
aniline

: 67623-10-3
(phenyl isonitrile)gold(I) chloride

: 136835-13-7
benzimidazolin-2-ylidene(chloro)gold

: 136835-16-0
chloro(dianilinocarbene)gold

Guidance literature:: In tetrahydrofuran; protective gas: argon; slow addn. of phenylamine (in THF) to stirred suspension of (ClAuCN)2C6H4 (70 h/room temp.);; filtration; evapn.; digestion (CH2Cl2/30 min); filtration (from C6H4(NH)2CAuCl); addn. of ether ppts. carben-gold complex; concn., further addn. of ether; pptn.;;
DOI:10.1016/0022-328X(91)86106-Z