(2,4-dichloro-phenyl)-methallyl ether

Base Information

• Chemical Name: (2,4-dichloro-phenyl)-methallyl ether
• CAS No.: 5820-26-8
• Molecular Formula: C₁₀H₁₀Cl₂O
• Molecular Weight: 217.095
• Mol file: 5820-26-8.mol

Synonyms:(2,4-dichloro-phenyl)-methallyl ether

Chemical Property of (2,4-dichloro-phenyl)-methallyl ether

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,4-dichloro-phenyl)-methallyl ether

There total 3 articles about (2,4-dichloro-phenyl)-methallyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

C16H5Cl6NO5 + prop-1-en-2-ylzinc(II) chloride (119441-91-7) → (2,4-dichloro-phenyl)-methallyl ether (5820-26-8)

Guidance literature:

With [2,2]bipyridinyl; bis(2,4-pentanedionate)nickel(II) hydrate; In tetrahydrofuran; N,N-dimethyl-formamide; at 20 ℃; chemoselective reaction;

DOI:10.1038/nature22307

Reference yield:

2,4-dichlorophenol (120-83-2,40477-79-0) + 3-Chloro-2-methylpropene (563-47-3) → (2,4-dichloro-phenyl)-methallyl ether (5820-26-8)

Guidance literature:

With potassium carbonate; acetone;

Reference yield:

2,4-Dichlorophenoxyacetic acid (94-75-7,89300-30-1) → (2,4-dichloro-phenyl)-methallyl ether (5820-26-8)

Guidance literature:

Multi-step reaction with 2 steps

1: diisopropyl-carbodiimide / dichloromethane

2: bis(2,4-pentanedionate)nickel(II) hydrate; [2,2]bipyridinyl / tetrahydrofuran; N,N-dimethyl-formamide / 20 °C

With [2,2]bipyridinyl; bis(2,4-pentanedionate)nickel(II) hydrate; diisopropyl-carbodiimide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;

DOI:10.1038/nature22307

upstream raw materials:

2,4-dichlorophenol

3-Chloro-2-methylpropene

prop-1-en-2-ylzinc(II) chloride

2,4-Dichlorophenoxyacetic acid

Downstream raw materials:

(2,4-dichloro-phenyl)-(2-methyl-propenyl)-ether

3-(2,4-dichloro-phenoxy)-2,2-dimethyl-cyclopropanecarboxylic acid ethyl ester

trans-3-<2,4-Dichlor-phenoxy>-2,2-dimethyl-cyclopropan-1-carbonsaeure

1-((E)-3-Bromo-2-methyl-allyloxy)-2,4-dichloro-benzene