N,N-Dimethylnonamide

Base Information

• Chemical Name: N,N-Dimethylnonamide
• CAS No.: 6225-08-7
• Molecular Formula: C11H23 N O
• Molecular Weight: 185.3064
• Hs Code.: 2924199090
• European Community (EC) Number: 612-975-5
• DSSTox Substance ID: DTXSID00211311
• Nikkaji Number: J106.787G
• Wikidata: Q83086207
• Mol file: 6225-08-7.mol

Synonyms:N,N-Dimethylnonamide;N,N-dimethylnonanamide;6225-08-7;N,N-dimethyl nonanamide;n,n-dimethylpelargonamide;SCHEMBL2484949;DTXSID00211311;AKOS009163476

Chemical Property of N,N-Dimethylnonamide

Chemical Property:

• Vapor Pressure: 0.0268mmHg at 25°C
• Boiling Point: 246.6°Cat760mmHg
• Flash Point: 92.5°C
• PSA: 20.31000
• Density: 0.863g/cm³
• LogP: 2.82520
• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 7
• Exact Mass: 185.177964357
• Heavy Atom Count: 13
• Complexity: 132

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCC(=O)N(C)C

Technology Process of N,N-Dimethylnonamide

There total 11 articles about N,N-Dimethylnonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Nonanoyl chloride (764-85-2) + dimethyl amine (124-40-3) → octanecarboxylic acid dimethylamide (6225-08-7)

Guidance literature:

With triethylamine; In dichloromethane; at 20 ℃; for 14h; Inert atmosphere;

DOI:10.1021/jacs.7b02983 DOI:10.1021/jacs.7b08813

Reference yield: 100.0%

N-Butyl-N-nitrosopelargonamide (91083-85-1) + dimethyl amine (124-40-3) → octanecarboxylic acid dimethylamide (6225-08-7)

Guidance literature:

In dichloromethane; at 40 ℃; for 8h;

DOI:10.1021/jo00192a014

Reference yield: 87.0%

N,N-Dimethyl-2-nonynamide (136616-82-5) → octanecarboxylic acid dimethylamide (6225-08-7)

Guidance literature:

With samarium diiodide; water; In tetrahydrofuran; at 20 ℃; for 0.5h;

DOI:10.1016/j.tetlet.2004.01.051

upstream raw materials:

oct-1-ene

N,N-dimethyl-formamide

Nonanoyl chloride

dimethyl amine

Downstream raw materials:

N,N-dimethylnonylamine

Refernces

• 1、 Zhou, Xibing,Zhang, Guoying,Gao, Bao,Huang, Hanmin. "Palladium-Catalyzed Hydrocarbonylative C-N Coupling of Alkenes with Amides". supporting information. p. 2208 - 2212. Retrieved 2018/04/30.
• 2、 Kaiser, Daniel,Teskey, Christopher J.,Adler, Pauline,Maulide, Nuno. "Chemoselective Intermolecular Cross-Enolate-Type Coupling of Amides". supporting information. p. 16040 - 16043. Retrieved 2017/11/22.