9-bromo-6-(4,6-diphenylpyrimidin-2-yl)-12,12-dimethyl-2-phenyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene

Base Information

Chemical Name:9-bromo-6-(4,6-diphenylpyrimidin-2-yl)-12,12-dimethyl-2-phenyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene
CAS No.:1307286-04-9
Molecular Formula:C₄₃H₃₀BrN₃
Molecular Weight:668.635
Hs Code.:

Synonyms:9-bromo-6-(4,6-diphenylpyrimidin-2-yl)-12,12-dimethyl-2-phenyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene

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Chemical Property of 9-bromo-6-(4,6-diphenylpyrimidin-2-yl)-12,12-dimethyl-2-phenyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene

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Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 9-bromo-6-(4,6-diphenylpyrimidin-2-yl)-12,12-dimethyl-2-phenyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene

There total 8 articles about 9-bromo-6-(4,6-diphenylpyrimidin-2-yl)-12,12-dimethyl-2-phenyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 1307286-01-6
6-(4,6-diphenylpyrimidin-2-yl)-12,12-dimethyl-2-phenyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene

: 1307286-04-9
9-bromo-6-(4,6-diphenylpyrimidin-2-yl)-12,12-dimethyl-2-phenyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene

Guidance literature:: With N-Bromosuccinimide; In acetonitrile; at -15 - 20 ℃; Darkness;

Reference yield:

: 577-19-5
2-nitrophenyl bromide

: 1307286-04-9
9-bromo-6-(4,6-diphenylpyrimidin-2-yl)-12,12-dimethyl-2-phenyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene

Guidance literature:: Multi-step reaction with 5 steps

1.1: tris-(o-tolyl)phosphine; palladium diacetate; potassium phosphate / toluene; water; 1,4-dioxane / 16 h / Reflux

2.1: triethyl phosphite / 12 h / Reflux

3.1: sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾ / N,N-dimethyl-formamide / 16 h / Reflux

4.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 20 °C / Inert atmosphere

4.2: 12 h / 20 °C

5.1: N-Bromosuccinimide / acetonitrile / -15 - 20 °C / Darkness

With potassium phosphate; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; palladium diacetate; sodium hydride; sodium carbonate; tris-(o-tolyl)phosphine; triethyl phosphite; In 1,4-dioxane; water; N,N-dimethyl-formamide; toluene; acetonitrile; mineral oil;

Reference yield:

: 98-80-6
phenylboronic acid

: 1307286-04-9
9-bromo-6-(4,6-diphenylpyrimidin-2-yl)-12,12-dimethyl-2-phenyl-6,12-dihydro-6-azaindeno[1,2-b]fluorene

Guidance literature:: Multi-step reaction with 3 steps

1.1: tris-(o-tolyl)phosphine; palladium diacetate; sodium hydrogencarbonate / 1,2-dimethoxyethane / 16 h / Reflux

2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / 20 °C / Inert atmosphere

2.2: 12 h / 20 °C

3.1: N-Bromosuccinimide / acetonitrile / -15 - 20 °C / Darkness

With N-Bromosuccinimide; palladium diacetate; sodium hydride; sodium hydrogencarbonate; tris-(o-tolyl)phosphine; In 1,2-dimethoxyethane; N,N-dimethyl-formamide; acetonitrile; mineral oil;