Anthracene, 2-methoxy- (6CI,7CI,9CI)

Base Information

• Chemical Name: Anthracene, 2-methoxy- (6CI,7CI,9CI)
• CAS No.: 42298-28-2
• Molecular Formula: C15H12 O
• Molecular Weight: 208.26
• Mol file: 42298-28-2.mol

Synonyms:2-Methoxyanthracene

Chemical Property of Anthracene, 2-methoxy- (6CI,7CI,9CI)

Chemical Property:

• PSA: 9.23000
• LogP: 4.00160

Purity/Quality:

98%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Anthracene, 2-methoxy- (6CI,7CI,9CI)

There total 14 articles about Anthracene, 2-methoxy- (6CI,7CI,9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-benzyl-5-methoxybenzaldehyde (1292302-64-7) → 2-methoxyanthracene (42298-28-2)

Guidance literature:

With boron trifluoride diethyl etherate; toluene-4-sulfonamide; In toluene; at 20 ℃; for 0.166667h;

DOI:10.1002/adsc.201000732

Reference yield: 93.0%

2-(3-methoxybenzyl)benzaldehyde (223575-85-7) → 2-methoxyanthracene (42298-28-2)

Guidance literature:

With indium(III) triflate; In 1,2-dichloro-ethane; at 25 ℃; for 1h; Inert atmosphere;

DOI:10.1021/jo200861s

Reference yield: 75.0%

2-methoxy-9(10H)-anthracenone (53604-95-8) → 2-methoxyanthracene (42298-28-2)

Guidance literature:

With sodium hydroxide; zinc; In toluene; for 24h; Heating;

DOI:10.1021/ja00011a036

upstream raw materials:

methanol

2-hydroxyanthracene

2-methoxy-9,10-anthraquinone

methyl iodide

Downstream raw materials:

[2]anthryl-phenyl-amine

1-cinnamoyl-2-methoxyanthracene

Refernces

• 1、 Wen, Fei,Li, Zheng. "Semicarbazide: A Transient Directing Group for C(sp3)?H Arylation of 2-Methylbenzaldehydes". supporting information. p. 133 - 138. Retrieved 2019/11/28.
• 2、 Mohammad-Pour, Gavin S.,Ly, Richard T.,Fairchild, David C.,Burnstine-Townley, Alex,Vazquez-Molina, Demetrius A.,Trieu, Khang D.,Campiglia, Andres D.,Harper, James K.,Uribe-Romo, Fernando J.. "Modular Design of Fluorescent Dibenzo- and Naphtho-Fluoranthenes: Structural Rearrangements and Electronic Properties". supporting information. p. 8036 - 8053. Retrieved 2018/05/31.