methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(3-methyl-6-methylsulfonyl)-2-hexenyl>-benzoate

Base Information

Chemical Name:methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(3-methyl-6-methylsulfonyl)-2-hexenyl>-benzoate
CAS No.:118607-98-0
Molecular Formula:C₁₉H₂₈O₁₁S₃
Molecular Weight:528.623
Hs Code.:

Synonyms:methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(3-methyl-6-methylsulfonyl)-2-hexenyl>-benzoate

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Chemical Property of methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(3-methyl-6-methylsulfonyl)-2-hexenyl>-benzoate

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Technology Process of methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(3-methyl-6-methylsulfonyl)-2-hexenyl>-benzoate

There total 9 articles about methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(3-methyl-6-methylsulfonyl)-2-hexenyl>-benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 124-63-0
methanesulfonyl chloride

: 118607-97-9
methyl (E)-2,4-dihydroxy-6-methyl-3<(3-methyl-6-ol)-2-hexenyl>-benzoate

: 118607-98-0
methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(3-methyl-6-methylsulfonyl)-2-hexenyl>-benzoate

Guidance literature:: With triethylamine; In dichloromethane; for 0.5h;
DOI:10.1016/S0040-4020(01)85090-0

Reference yield:

: 86864-59-7
5-((tert-butyldimethylsilyl)oxy)pentan-2-one

: 118607-98-0
methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(3-methyl-6-methylsulfonyl)-2-hexenyl>-benzoate

Guidance literature:: Multi-step reaction with 6 steps

1: 17.25 g / NaH / tetrahydrofuran; hexane; diethyl ether / 40 h / Ambient temperature

2: 96 percent / DIBAL / CH₂Cl₂ / -78 deg C, 1 h, then 0 deg C

3: CBr₄, Ph₃P / CH₂Cl₂ / 1 h / -78 °C

4: 3.10 g / toluene / 12 h / Heating

5: 89 percent / tetrabutylammonium fluoride / tetrahydrofuran / 4 h

6: 100 percent / triethylamine / CH₂Cl₂ / 0.5 h

With carbon tetrabromide; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; triethylamine; triphenylphosphine; In tetrahydrofuran; diethyl ether; hexane; dichloromethane; toluene;
DOI:10.1016/S0040-4020(01)85090-0

Reference yield:

: 118607-92-4
6-bromo-4-methyl-4(E)-hexenyl tert-butyldimethylsilyl ether

: 118607-98-0
methyl (E)-2,4-di(methylsulfonyl)-6-methyl-3-<(3-methyl-6-methylsulfonyl)-2-hexenyl>-benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: 3.10 g / toluene / 12 h / Heating

2: 89 percent / tetrabutylammonium fluoride / tetrahydrofuran / 4 h

3: 100 percent / triethylamine / CH₂Cl₂ / 0.5 h

With tetrabutyl ammonium fluoride; triethylamine; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1016/S0040-4020(01)85090-0