(Z)-[2-(dicyclopentadienylchlorozircono)-1,2-dibutylvinyl]diisopropylphosphine

Base Information

Chemical Name:(Z)-[2-(dicyclopentadienylchlorozircono)-1,2-dibutylvinyl]diisopropylphosphine
CAS No.:930576-69-5
Molecular Formula:C₂₆H₄₂ClPZr
Molecular Weight:512.27
Hs Code.:

Synonyms:(Z)-[2-(dicyclopentadienylchlorozircono)-1,2-dibutylvinyl]diisopropylphosphine

Suppliers and Price of (Z)-[2-(dicyclopentadienylchlorozircono)-1,2-dibutylvinyl]diisopropylphosphine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of (Z)-[2-(dicyclopentadienylchlorozircono)-1,2-dibutylvinyl]diisopropylphosphine

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (Z)-[2-(dicyclopentadienylchlorozircono)-1,2-dibutylvinyl]diisopropylphosphine

There total 1 articles about (Z)-[2-(dicyclopentadienylchlorozircono)-1,2-dibutylvinyl]diisopropylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 1291-32-3
zirconocene dichloride

: 1942-46-7
5-decyne

: 40244-90-4
Chlorodiisopropylphosphane

: 930576-69-5
(Z)-[2-(dicyclopentadienylchlorozircono)-1,2-dibutylvinyl]diisopropylphosphine

Guidance literature:: With dmap; n-butyllithium; In tetrahydrofuran; hexane; (N2); Schlenk technique; soln. of BuLi in hexane added to soln. of Zr complex in THF at -78°C; stirred at -78°C for 1 h; pyridine added; stirred at room temp. for 1 h; alkyne added; stirred for 1 h; P ligand added; stirred for 1 h; NMR monitoring; evapd. (vac.); washed (3 N HCl); extd. (CH2Cl2); solventremoved; chromd. (silica gel, petroleum ether/THF, 1/1); elem. anal.;
DOI:10.1021/om061051t